High-valent manganese(v)-oxo porphyrin complexes in hydride transfer reactions

被引：42
|
作者：
Lee, Jung Yoon [1 ]
Lee, Yong-Min [1 ]
Kotani, Hiroaki [2 ]
Nam, Wonwoo [1 ]
Fukuzumi, Shunichi [2 ]
机构：
[1] Ewha Womans Univ, Dept Chem & Nano Sci, Ctr Biomimet Syst, Seoul 120750, South Korea
[2] Osaka Univ, Dept Mat & Life Sci, Grad Sch Engn, SORST,Japan Sci & Technol Agcy, Suita, Osaka 5650871, Japan
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 06期
关键词：
PHOTOINDUCED ELECTRON-TRANSFER; OXYGEN-ATOM TRANSFER; OXOMANGANESE(V) PORPHYRIN; RADICAL CATIONS; NADH ANALOGS; 9-SUBSTITUTED 10-METHYL-9,10-DIHYDROACRIDINES; TRANSFER OXIDATION; C-H; OXO; REACTIVITIES;
D O I：
10.1039/b814928c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to trans-dioxomanganese(v) porphyrin complexes proceeds via proton-coupled electron transfer, followed by rapid electron transfer.
引用
收藏
页码：704 / 706
页数：3
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