A mild and efficient oxidation of alcohols to carbonyl compounds by periodic acid catalyzed by 2,2,6,6-tetramethylpiperidinyi-1-oxyl

被引:0
|
作者
Kim, SS [1 ]
Nehru, K
机构
[1] Inha Univ, Dept Chem, Inchon 402751, South Korea
[2] Inha Univ, Ctr Chem Dynam, Inchon 402751, South Korea
关键词
oxidations; TEMPO; periodic acid; alcohols; carbonyls;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Numerous alcohols are effectively oxidized to corresponding aldehydes and ketones with H5IO6-TEMPO. The rate of oxidation parallels decreasing alpha-C-H bond dissociation energy, that is secondary alcohols react faster than primary alcohols.
引用
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页码:616 / 618
页数:3
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