STUDIES ON THE PALLADIUM AND GOLD IONS EXTRACTION WITH SOME ESTER DERIVATIVES OF CALIX[N]ARENE

被引:0
|
作者
Saponar, Alina [1 ]
Popovici, Elisabeth-Jeanne [1 ]
Perhaita, Ioana [1 ]
Nemes, Gabriela [2 ]
机构
[1] Univ Babes Bolyai, Raluca Ripan Inst Res Chem, Cluj Napoca 400294, Romania
[2] Univ Babes Bolyai, Fac Chem & Chem Engn, Cluj Napoca 40084, Romania
来源
关键词
Calixarene; liquid-liquid extraction; metal ions; ARSENATE; RECEPTORS; EFFICIENT; CHROMATE;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The capability of p-tert-butyl calix[n]arene [n = 4,6,8] functionalized at the lower rim with a variable number of ethyl acetate groups to extract palladium and gold ions from aqueous medium has been investigated. The influence of reagent molar ratio, acidity of the medium and time on the extraction efficiency was investigated by monitoring the concentration of the metallic ions from aqueous solution. In most of the cases, the half substituted calix[n]arene derivatives show a relative high extraction efficiency and are of interest as liquid-liquid extraction reagents for precious metal ions.
引用
收藏
页码:157 / 168
页数:12
相关论文
共 50 条
  • [31] Spectroscopic study of molecular recognition of ions by chromogenic calix[4]arene derivatives
    Mohammed-Ziegler, I.
    Poór, B.
    Kubinyi, M.
    Grofcsik, A.
    Grün, A.
    Bitter, I.
    Journal of Inclusion Phenomena, 1999, 35 (1-2): : 349 - 353
  • [32] Liquid-liquid extraction and transport through membrane of amino acid methylesters by calix[n]arene derivatives
    Mutihac, Lucia
    Mutihac, Radu
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2007, 59 (1-2) : 177 - 181
  • [33] Extraction Behavior of Amino Acids by Calix[6]arene Carboxylic Acid Derivatives
    Tatsuya Oshima
    Masahiro Goto
    Shintaro Furusaki
    Journal of inclusion phenomena and macrocyclic chemistry, 2002, 43 : 77 - 86
  • [34] Polymer Supported Calix[4]Arene Derivatives for the Extraction of Metals and Dichromate Anions
    Shahabuddin Memon
    Ezgi Akceylan
    Begum Sap
    Mustafa Tabakci
    D. Max Roundhill
    Mustafa Yilmaz
    Journal of Polymers and the Environment, 2003, 11 : 67 - 74
  • [35] Liquid-liquid extraction of transition metal cations by nine new azo derivatives calix[n]arene
    Akdogan, A
    Deniz, M
    Cebecioglu, S
    Sen, A
    Deligöz, H
    SEPARATION SCIENCE AND TECHNOLOGY, 2002, 37 (04) : 973 - 980
  • [36] Polymer supported calix[4] arene derivatives for the extraction of metals and dichromate anions
    Memon, S
    Akceylan, E
    Sap, B
    Tabakci, M
    Roundhill, DM
    Yilmaz, M
    JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2003, 11 (02) : 67 - 74
  • [37] Synthesis of two calix[4]arene diamide derivatives for extraction of chromium(VI)
    Bozkurt, S
    Karakucuk, A
    Sirit, A
    Yilmaz, M
    TETRAHEDRON, 2005, 61 (44) : 10443 - 10448
  • [38] Synthesis and extraction studies of polymeric phthalimido functionalized calix[4]arene
    Gülderen Uysal Akkuş
    Cihangir Cebeci
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2008, 62 : 303 - 309
  • [39] Synthesis and extraction studies of polymeric phthalimido functionalized calix[4]arene
    Akkus, Guelderen Uysal
    Cebeci, Cihangir
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2008, 62 (3-4) : 303 - 309
  • [40] Extraction behavior of amino acids by calix[6] arene carboxylic acid derivatives
    Oshima, T
    Goto, M
    Furusaki, S
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2002, 43 (1-2) : 77 - 86