Facile synthesis of metal-organic framework MIL-101 from 4-NIm-Cr(NO3)3-H2BDC-H2O

被引：16
作者：
Chen, Heng [1 ]
Chen, Shaoyun [1 ]
Yuan, Xingzhou [1 ]
Zhang, Yongchun [1 ]
机构：
[1] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116023, Liaoning, Peoples R China
来源：
MATERIALS LETTERS | 2013年 / 100卷
关键词：
Porous materials; Metal-organic framework; Functional; MIL-101; Synthesis; 4-Nitroimidazole;
D O I：
10.1016/j.matlet.2013.03.053
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The aim of this paper is to introduce a nitro-containing group into the Cr-MIL-101 framework using 4-nitroimidozle (4-NIm) and 1,4-benzenedicarboxylic acid (H2BDC) as co-ligand. Cr-MIL-101 was synthesized at 423 K from 4-NIm-Cr(NO3)(3)-H2BDC-H2O for the first time. A yield of 89% was obtained by comparing the chromium content in the material after and before synthesis. The FT-IR spectrum showed that there were no free H2BDC and nitro-group in the Cr-MIL-101(4-NIm) sample. 4-NIm must have played a different role in the synthesis. The XRD patterns and SEM photos confirmed the octahedral crystal configuration of Cr-MIL-101(4-NIm) which would be a potential material for CO2 adsorption. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：230 / 232
页数：3
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