Carbon dioxide capture capacity of sodium hydroxide aqueous solution

被引：189

作者：

Yoo, Miran ^{[1
]}

Han, Sang-Jun ^{[1
]}

Wee, Jung-Ho ^{[1
]}

机构：

[1] Catholic Univ Korea, Dept Environm Engn, Bucheon Si 420743, Gyeonggi Do, South Korea

来源：

JOURNAL OF ENVIRONMENTAL MANAGEMENT | 2013年 / 114卷

基金：

新加坡国家研究基金会;

关键词：

Climate change; Carbon capture; Chemical absorption; Greenhouse gas; Absorbent; Sodium hydroxide; MASS-TRANSFER; CO2; ABSORPTION; CHEMICAL ABSORPTION; NAOH SOLUTION; MODEL; COLUMN; CHEMISORPTION; CORROSION; PACKINGS; KINETICS;

D O I：

10.1016/j.jenvman.2012.10.061

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The present paper investigates the various features of NaOH aqueous solution when applied as an absorbent to capture carbon dioxide (CO2) emitted with relatively high concentration in the flue gas. The overall CO2 absorption reaction was carried out according to consecutive reaction steps that are generated in the order of Na2CO3 and NaHCO3. The reaction rate and capture efficiency were strongly dependent on the NaOH concentration in the Na2CO3 production range, but were constant in the NaHCO3 production step, irrespective of the NaOH concentration. The amount of CO2 absorbed in the solution was slightly less than the theoretical value, which was ascribed to the low trona production during the reaction and the consequent decrease in CO2 absorption in the NaOH solution. The mass ratio of absorbed CO2 that participated in the Na2CO3, NaHCO3, and trona production reactions was calculated to be 20:17:1, respectively. (c) 2012 Elsevier Ltd. All rights reserved.

引用

页码：512 / 519

页数：8

共 38 条

[1] Behavior of the mass-transfer coefficient of structured packings in CO2 absorbers with chemical reactions [J].

Aroonwilas, A ;

Veawab, A ;

Tontiwachwuthikul, P .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1999, 38 (05) :2044-2050

[2] Effects of operating and design parameters on CO2 absorption in columns with structured packings [J].

Aroonwilas, A ;

Tontiwachwuthikul, P ;

Chakma, A .

SEPARATION AND PURIFICATION TECHNOLOGY, 2001, 24 (03) :403-411

[3] Mass transfer study and modeling of gas-liquid membrane contacting process by multistage cascade model for CO2 absorption [J].

Atchariyawut, Supakorn ;

Jiraratananon, Ratana ;

Wang, Rong .

SEPARATION AND PURIFICATION TECHNOLOGY, 2008, 63 (01) :15-22

[4] Process design and energy requirements for the capture of carbon dioxide from air [J].

Baciocchi, Renato ;

Storti, Giuseppe ;

Mazzotti, Marco .

CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2006, 45 (12) :1047-1058

[5] Removal of carbon dioxide by a spray dryer [J].

Chen, JC ;

Fang, GC ;

Tang, JT ;

Liu, LP .

CHEMOSPHERE, 2005, 59 (01) :99-105

[6] Gas-phase mass-transfer measurements in a falling-film microreactor [J].

Commenge, J. -M ;

Obein, T. ;

Framboisier, X. ;

Rode, S. ;

Pitiot, P. ;

Matlosz, M. .

CHEMICAL ENGINEERING SCIENCE, 2011, 66 (06) :1212-1218

[7] CO2 Absorption in a Microstructured Mesh Reactor [J].

Constantinou, Achilleas ;

Gavriilidis, Asterios .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (03) :1041-1049

[8] Detailed modelling of hydrodynamics, mass transfer and chemical reactions in a bubble column using a discrete bubble model:: Chemisorption of CO2 into NaOH solution, numerical and experimental study [J].

Darmana, D. ;

Henket, R. L. B. ;

Deen, N. G. ;

Kuipers, J. A. M. .

CHEMICAL ENGINEERING SCIENCE, 2007, 62 (09) :2556-2575

[9] Nonisothermal decomposition kinetics of trona [J].

Ekmekyapar, A ;

Ersahan, H ;

Yapici, S .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1996, 35 (01) :258-262

[10] Detailed modeling of the chemisorption of CO2 into NaOH in a bubble column [J].

Fleischer, C ;

Becker, S ;

Eigenberger, G .

CHEMICAL ENGINEERING SCIENCE, 1996, 51 (10) :1715-1724

← 1 2 3 4 →