Facile and economical exfoliation of graphite for mass production of high-quality graphene sheets

被引:82
作者
Lin, Tianquan [1 ,2 ]
Chen, Jian [1 ]
Bi, Hui [1 ]
Wan, Dongyun [1 ]
Huang, Fuqiang [1 ,2 ]
Xie, Xiaoming [3 ]
Jiang, Mianheng [3 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, Shanghai 200050, Peoples R China
[2] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
[3] Chinese Acad Sci, Shanghai Inst Microsyst & Informat Technol, State Key Lab Funct Mat Informat, Shanghai, Peoples R China
关键词
NANOSHEETS; OXIDE; FILMS;
D O I
10.1039/c2ta00518b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We simulate a micromechanical exfoliation process to design a simple but effective and low-cost strategy for mass production of high-quality graphene sheets by planetary milling with oxalic acid. The selective carboxylation enables oxalic acid molecules to adhere to the edge and defects of graphite like a Scotch tape and plays a crucial role in the non-destructive exfoliation.
引用
收藏
页码:500 / 504
页数:5
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