Promising activated carbons derived from waste tea-leaves and their application in high performance supercapacitors electrodes

被引:449
作者
Peng, Chao [1 ,2 ,3 ]
Yan, Xing-bin [1 ,2 ]
Wang, Ru-tao [1 ,2 ]
Lang, Jun-wei [1 ,2 ]
Ou, Yu-jing [2 ]
Xue, Qun-ji [2 ]
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Clean Energy Chem & Mat, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
[3] Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Peoples R China
关键词
Activated carbon; Tea-leaves; Supercapacitors; Carbonization; Activation; CHEMICAL ACTIVATION; MESOPOROUS CARBON; NANOPOROUS CARBON; KOH ACTIVATION; SURFACE-AREA; POROSITY; CAPACITORS; ACCESSIBILITY; COMPOSITES; ADSORPTION;
D O I
10.1016/j.electacta.2012.09.082
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In this paper, five types of waste tea-leaves, which come from five of the most typical tea in China, are first used to prepare activated carbons (ACs) by high-temperature carbonization and activation with KOH. The resulting ACs show typical amorphous character, and display porous structures with high specific surface areas ranging from 2245 m(2) g(-1) to 2841 m(2) g(-1). As the electro-active electrode materials, the as-made five ACs exhibit ideal capacitive behaviors in aqueous KOH electrolyte, and the maximal specific capacitance is as high as 330 F g(-1) at the current density of 1 A g(-1). Furthermore, they all show excellent electrochemical cycle stability with similar to 92% initial capacitance being retained after 2000 cycles. The desirable capacitive performances enable the waste tea-leaves to act as a new biomass source of carbonaceous materials for high performance supercapacitors and low-cost energy storage devices. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:401 / 408
页数:8
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