Cu complexes that catalyze the oxygen reduction reaction

被引：177

作者：

Thorseth, Matthew A. ^{[1
]}

Tornow, Claire E. ^{[1
]}

Tse, Edmund C. M. ^{[1
]}

Gewirth, Andrew A. ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2013年 / 257卷 / 01期

关键词：

Oxygen reduction reaction (ORR); Cu catalysts; Electrochemistry; FUEL-CELL APPLICATIONS; GRAPHITE-ELECTRODES; DIOXYGEN REDUCTION; ELECTROCATALYTIC REDUCTION; O-2; ELECTROREDUCTION; COPPER COMPLEX; 4-ELECTRON REDUCTION; MECHANISTIC ASPECTS; IMIDAZOLE LIGANDS; CRYSTAL-STRUCTURE;

D O I：

10.1016/j.ccr.2012.03.033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The oxygen reduction reaction (ORR) is employed in a large number of systems such as fuel cells and air batteries. Currently, the catalyst with the lowest overpotential for the ORR is the enzyme laccase. Laccase only functions at a very narrow pH range, and its large size prevents high current densities. Using copper based catalysts to mimic the ORR activity is an area with many spectroscopic results, but relatively few electrochemical studies. This review catalogs the various copper based ORR catalysts and their activities. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：130 / 139

页数：10

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