Hexaaquacopper(II) dinitrate: absence of Jahn-Teller distortion

被引:7
|
作者
Zibaseresht, R [1 ]
Hartshorn, RM [1 ]
机构
[1] Univ Canterbury, Dept Chem, Christchurch 4800, New Zealand
关键词
D O I
10.1107/S1600536805041851
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cu(H2O)(6)](NO3)(2), the geometry around the Cu II ion is approximately octahedral, formed by six O atoms from the coordinated water molecules. The Cu-O distances are rather similar [2.014 (2)-2.084 (2) angstrom] and not related by symmetry. The Jahn-Teller effect is, at best, only weakly observed in this structure, in contrast to many other structures where the hexaaquacopper( II) ion has been characterized. An extensive mesh of hydrogen-bond interactions between the coordinated water molecules and nitrate ions is a feature of the structure and may limit the degree to which the Jahn-Teller effect can be observed.
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页码:I19 / I22
页数:4
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