EFFECT OF PYROLYSIS TEMPERATURE ON CHEMICAL AND SURFACE PROPERTIES OF BIOCHAR OF RAPESEED (BRASSICA NAPUS L.)

被引:100
作者
Angin, Dilek [1 ]
Sensoz, Sevgi [2 ]
机构
[1] Sakarya Univ, Dept Food Engn, Fac Engn, TR-54187 Sakarya, Turkey
[2] Eskisehir Osmangazi Univ, Dept Chem Engn, Fac Engn & Architecture, Eskisehir, Turkey
关键词
rapeseed; pyrolysis; biochar; characterization; BIO-OIL; CARBON SEQUESTRATION; RICE HUSK; CHAR; BIOMASS; CAKE; FRACTIONS; FEATURES; STONES; SLUDGE;
D O I
10.1080/15226514.2013.856842
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The biochar is an important carbon-rich product that is generated from biomass sources through pyrolysis. Biochar (charcoal) can be both used directly as a potential source of solid biofuels and as soil amendments for barren lands. The aim of this study was investigate influence of pyrolysis temperature on the physicochemical properties and structure of biochar. The biochars were produced by pyrolysis of rapeseed (Brassica napus L.) using a fixed-bed reactor at different pyrolysis temperatures (400-700 degrees C). The produced biochars were characterized by proximate and elemental analysis, Brunauer-Emmett-Teller (BET) surface area, particle size distributions, scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy. The results showed that both chemical and surface properties of the biochars were significantly affected by the pyrolysis temperature.Aromatic hydrocarbons, hydroxyl and carbonyl compounds were the majority components of the biochar. The biochar obtained at 700 degrees C had a high fixed carbon content (66.16%) as well as a high heating value, and therefore it could be used as solid fuel, precursor in the activated carbons manufacture (specific surface area until 25.38m(2) g(-1)), or to obtain category-A briquettes.
引用
收藏
页码:684 / 693
页数:10
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