Infiltration of ionic-, electronic- and mixed-conducting nano particles into La0.75Sr0.25MnO3-Y0.16Zr0.84O2 cathodes - A comparative study of performance enhancement and stability at different temperatures

被引：45
作者：
Kiebach, Ragnar [1 ]
Knofel, Christina [1 ]
Bozza, Francesco [1 ]
Klemenso, Trine [1 ]
Chatzichristodoulou, Christodoulos [1 ]
机构：
[1] Tech Univ Denmark, Dept Energy Convers & Storage, DK-4000 Roskilde, Denmark
来源：
JOURNAL OF POWER SOURCES | 2013年 / 228卷
关键词：
Solid oxide fuel cell; LSM cathode; Infiltration; Impregnation; Nano particle; OXIDE FUEL-CELLS; STRUCTURED ELECTRODES; IMPEDANCE; NI; IMPREGNATION; COMPOSITE;
D O I：
10.1016/j.jpowsour.2012.11.070
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The microstructure and electrochemical performance of LSM-YSZ composite electrodes infiltrated with La0.8Sr0.2MnO3-delta (LSM) as an electronic conductor, LaCo0.6Ni0.4O3-delta (LCN) as a mixed conductor and Ce0.8Gd0.2O2-delta (CGO) as an ionic conductor, were compared in the temperature range 550-800 degrees C. All three infiltrates resulted in improved electrochemical performance. Impedance analysis suggested dissociative adsorption and transfer of species to the triple phase boundary as the main mechanism responsible for the performance enhancement in all cases, attributed to the increase in surface area and triple phase boundary upon infiltration. LCN showed the most pronounced improvement at 550 degrees C, but its performance degraded drastically with increasing temperature. LSM and CGO infiltrated electrodes degraded less upon heating up to 800 degrees C. Infiltrated CGO electrodes showed the smallest degradation rate upon long term testing at 750 degrees C. (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：170 / 177
页数：8
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