Polymer@MOF@MOF: "grafting from" atom transfer radical polymerization for the synthesis of hybrid porous solids

被引：102

作者：

McDonald, Kyle A. ^{[1
]}

Feldblyum, Jeremy I. ^{[2
]}

Koh, Kyoungmoo ^{[1
]}

Wong-Foy, Antek G. ^{[1
]}

Matzger, Adam J. ^{[1
,2
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

[2] Univ Michigan, Macromol Sci & Engn, Ann Arbor, MI 48109 USA

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 60期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORK; GAS SEPARATION; FUTURE PERSPECTIVES; ASSEMBLY STRATEGY; CORE-SHELL; MEMBRANES; CARBON; FUNCTIONALIZATION; STORAGE;

D O I：

10.1039/c5cc03027g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The application of a core-shell architecture allows the formation of a polymer-coated metal-organic framework (MOF) maintaining high surface area (2289-2857 m(2) g(-1)). The growth of a MOF shell from a MOF core was used to spatially localize initiators by post-synthetic modification. The confinement of initiators ensures that polymerization is restricted to the outer shell of the MOF.

引用

收藏

页码：11994 / 11996

页数：3

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