An unprecedented bonding mode for potassium within a PCP-pincer palladium hydride-K-Selectride® complex

被引：10

作者：

Boro, Brian J. ^{[1
]}

Duesler, Eileen N. ^{[1
]}

Goldberg, Karen I. ^{[2
]}

Kemp, Richard A. ^{[1
,3
]}

机构：

[1] Univ New Mexico, Dept Chem & Biol Chem, Albuquerque, NM 87131 USA

[2] Univ Washington, Dept Chem, Seattle, WA 98195 USA

[3] Sandia Natl Labs, Adv Mat Lab, Albuquerque, NM 87106 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 12期

基金：

美国国家科学基金会;

关键词：

Tridentate ligands; Pd complexes; Crystal structure; Hydride ligands;

D O I：

10.1016/j.inoche.2008.09.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of (PCP)i-PrPdCl and the commonly-used reductant K-Selectride (R) solution [K(sec-Bu3BH) in THF] does not yield a simple (PCP)i-PrPdH species, but rather an adduct of the Pd-H that contains bound K(sec-Bu3BH). This adduct has been characterized by X-ray crystallography and shown to be a centrosymmetric dimer in the solid state. The most unique feature of the structure is that the tri-coordinate K+ ion bonds only to the terminal palladium hydride and the two bridging boron hydrides. Despite being prepared in THF, no other donor ligands are bound to K+. This [H3K](+) bonding mode for K+ ions has not been previously reported. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：1426 / 1429

页数：4

共 2 条

[1] A hexanuclear iridium complex with a novel binding mode of a PCP-pincer ligand
Zhang, XW
Emge, TJ
Goldman, AS
INORGANICA CHIMICA ACTA, 2004, 357 (10) : 3014 - 3018
[2] Catalytic amine-borane dehydrogenation by a PCP-pincer palladium complex: a combined experimental and DFT analysis of the reaction mechanism
Rossin, Andrea
Bottari, Giovanni
Lozano-Vila, Ana M.
Paneque, Margarita
Peruzzini, Maurizio
Rossi, Andrea
Zanobini, Fabrizio
DALTON TRANSACTIONS, 2013, 42 (10) : 3533 - 3541

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