Exceptional Steric Congestion in an in,in-Bis(hydrosilane)

被引：38

作者：

Zong, Jie ^{[1
]}

Mague, Joel T. ^{[1
]}

Pascal, Robert A., Jr. ^{[1
]}

机构：

[1] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 36期

基金：

美国国家科学基金会;

关键词：

CYCLOPHANES; HYDROGEN;

D O I：

10.1021/ja407398w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and characterization of a macrobicyclic in,in-bis(hydrosilane) is described. A combination of crystallographic and computational data indicate that the central hydrogen-hydrogen nonbonded contact distance is the shortest for any crystallographically characterized compound.

引用

页码：13235 / 13237

页数：3

共 13 条

[11] SMALL, STRAINED CYCLOPHANES WITH METHINE HYDROGENS PROJECTED TOWARD THE CENTERS OF AROMATIC RINGS [J].