Exceptional Steric Congestion in an in,in-Bis(hydrosilane)

被引：38

作者：

Zong, Jie ^{[1
]}

Mague, Joel T. ^{[1
]}

Pascal, Robert A., Jr. ^{[1
]}

机构：

[1] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 36期

基金：

美国国家科学基金会;

关键词：

CYCLOPHANES; HYDROGEN;

D O I：

10.1021/ja407398w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and characterization of a macrobicyclic in,in-bis(hydrosilane) is described. A combination of crystallographic and computational data indicate that the central hydrogen-hydrogen nonbonded contact distance is the shortest for any crystallographically characterized compound.

引用

收藏

页码：13235 / 13237

页数：3

相关论文

共 13 条

[1] In/out isomerism [J].

Alder, RW ;

East, SP .

CHEMICAL REVIEWS, 1996, 96 (06) :2097-2111

[2] MAGNETIC DESHIELDING OF PROTONS DUE TO INTRAMOLECULAR STERIC INTERACTIONS WITH PROXIMATE HYDROGENS [J].

CHENEY, BV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (20) :5386-&

[3] SOME COMMENTS ON CARBON-HYDROGEN AND NITROGEN-HYDROGEN DISTANCES ASSUMED IN, AND DETERMINED FROM, RECENT X-RAY-DIFFRACTION STUDIES ON INORGANIC COMPLEXES [J].

CHURCHILL, MR .

INORGANIC CHEMISTRY, 1973, 12 (05) :1213-1214

[4] ULTRASHORT NONBONDED H ... H DISTANCE IN A HALF-CAGE PENTACYCLODODECANE [J].

ERMER, O ;

MASON, SA ;

ANET, FAL ;

MIURA, SS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (08) :2330-2334

[5]

Frisch M. J., 2016, Gaussian 03 Revision B.03

[6] PREPARATION, STRUCTURE, AND CONFORMATIONAL BEHAVIOR OF STRAINED ADAMANTANOPHANES [J].

LEMMERZ, R ;

NIEGER, M ;

VOGTLE, F .

CHEMISCHE BERICHTE-RECUEIL, 1994, 127 (06) :1147-1156

[7] IN-CYCLOPHANES CONTAINING 2ND-ROW ELEMENTS POISED ABOVE AROMATIC RINGS [J].

LESPERANCE, RP ;

WEST, AP ;

VANENGEN, D ;

PASCAL, RA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (07) :2672-2676

[8]

Lukevics E., 1989, MOL STRUCTURE ORGANO, P12

[9] Molecular "iron maidens": Ultrashort nonbonded contacts in cyclophanes and other crowded molecules [J].

Pascal, RA .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2004, 2004 (18) :3763-3771

[10] A concise set of "large", symmetric molecules for evaluation of modern computational methods [J].

Pascal, RA .

JOURNAL OF PHYSICAL CHEMISTRY A, 2001, 105 (39) :9040-9048