A study of the synthesis of endohedral metallofullerenes and empty fullerenes by the carbon-arc and RFICP technique

被引：10

作者：

Tran, NE ^{[1
]}

Lagowski, JJ ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

CARBON | 2002年 / 40卷 / 06期

关键词：

fullerene; arc discharge; plasma reactions; mass spectrometry;

D O I：

10.1016/S0008-6223(01)00228-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Fullerenes and endohedral metallofullerenes (M-x @C-2n; M=La, Mn, Nb, Au, and Li; x = 1-3, n greater than or equal to 30) were synthesized by two different techniques: the standard carbon-arc technique and a modification involving an RF-inductivc coupled plasma discharge. Both techniques employ a modified carbon-arc reactor which is durable, easy to operate, and capable of providing a high degree of control over many parameters of the reaction. Our results suggest that both fullerenes and endohedral metallofullerenes are formed by a radical pathway. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：939 / 948

页数：10

共 50 条

[21] Arc discharge synthesis of metallofullerenes using a carbon electrode with chemically modified surface
Kuzmin, S. M.
Borovkov, N. Yu.
Kolker, A. M.
HYDROGEN MATERIALS SCIENCE AND CHEMISTRY OF CARBON NANOMATERIALS, 2007, : 829 - +
[22] SIMULTANEOUS DETERMINATION OF OXYGEN + NITROGEN IN REFRACTORY METALS BY DIRECT CURRENT CARBON-ARC GAS CHROMATOGRAPHIC TECHNIQUE
WINGE, RK
FASSEL, VA
ANALYTICAL CHEMISTRY, 1965, 37 (01) : 67 - &
[23] SIMULTANEOUS DETERMINATION OF OXYGEN AND NITROGEN IN STEELS BY A D.C. CARBON-ARC, GAS CHROMATOGRAPHIC TECHNIQUE
EVENS, FM
FASSEL, VA
ANALYTICAL CHEMISTRY, 1963, 35 (10) : 1444 - &
[24] Synthesis and study of carbon nanomaterials through arc discharge technique for efficient adsorption of organic dyes
Madhurima, V. P.
Kumari, Kusum
Jain, P. K.
DIAMOND AND RELATED MATERIALS, 2024, 141
[25] Large scale synthesis of carbon nanotubes by plasma rotating arc discharge technique
Lee, SJ
Baik, HK
Yoo, JE
Han, JH
DIAMOND AND RELATED MATERIALS, 2002, 11 (3-6) : 914 - 917
[26] Synthesis of single wall carbon nanotubes by using arc discharge technique in nitrogen atmosphere
Makita, Y
Suzuki, S
Kataura, H
Achiba, Y
EUROPEAN PHYSICAL JOURNAL D, 2005, 34 (1-3): : 287 - 289
[27] Synthesis of single wall carbon nanotubes by using arc discharge technique in nitrogen atmosphere
Y. Makita
S. Suzuki
H. Kataura
Y. Achiba
The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics, 2005, 34 : 287 - 289
[28] Aligning carbon nanotubes, synthesized using the arc discharge technique, during and after synthesis
Berkmans, A. Joseph
Ramakrishnan, S.
Jain, Gaurav
Haridoss, Prathap
CARBON, 2013, 55 : 185 - 195
[29] Synthesis of high quality single-walled carbon nanotube silks by the arc discharge technique
Zhu, HW
Jiang, B
Xu, CL
Wu, DH
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (27): : 6514 - 6518
[30] A parametric study on the synthesis of carbon nanotubes through arc-discharge in water
Bera, D
Johnston, G
Heinrich, H
Seal, S
NANOTECHNOLOGY, 2006, 17 (06) : 1722 - 1730

← 1 2 3 4 5 →