Oxidative N-dealkylation in cobalt-bispidine-H2O2 systems

被引：31

作者：

Comba, P ^{[1
]}

Kuwata, S ^{[1
]}

Linti, G ^{[1
]}

Pritzkow, H ^{[1
]}

Tarnai, M ^{[1
]}

Wadepohl, H ^{[1
]}

机构：

[1] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 19期

关键词：

D O I：

10.1039/b602571d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the Co-II complex with the rigid bispidine ligand L-1 with two tertiary amine and two pyridine donors, [Co-II(L-1)(OH2)(2)](2+), with H2O2 and O-2 produces [Co-II(L-2) (OH2)(2)](3+), where L-2 is demethylated at one of the amine donors, and CH2O.

引用

页码：2074 / 2076

页数：3

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