Oxidative N-dealkylation in cobalt-bispidine-H2O2 systems

被引：31

作者：

Comba, P ^{[1
]}

Kuwata, S ^{[1
]}

Linti, G ^{[1
]}

Pritzkow, H ^{[1
]}

Tarnai, M ^{[1
]}

Wadepohl, H ^{[1
]}

机构：

[1] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 19期

关键词：

D O I：

10.1039/b602571d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the Co-II complex with the rigid bispidine ligand L-1 with two tertiary amine and two pyridine donors, [Co-II(L-1)(OH2)(2)](2+), with H2O2 and O-2 produces [Co-II(L-2) (OH2)(2)](3+), where L-2 is demethylated at one of the amine donors, and CH2O.

引用

页码：2074 / 2076

页数：3

共 36 条

[11] Slow electron self-exchange in spite of a small inner-sphere reorganisation energy - The electron-transfer properties of a copper complex with a tetradentate bispidine ligand [J].

Comba, P ;

Kerscher, M ;

Roodt, A .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (23) :4640-4645

[12] Bispidine copper(II) compounds: Effects of the rigid ligand backbone [J].

Comba, P ;

Lienke, A .

INORGANIC CHEMISTRY, 2001, 40 (20) :5206-5209

[13] OXIDATIVE CLEAVAGE OF AMINES BY AQUEOUS BROMINE AT 25 DEGREES [J].

DENO, NC ;

FRUIT, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (13) :3502-&

[14]

Gebbink RJMK, 1999, INORG CHEM, V38, P5755

[15] HYDROXYLATION BY CYTOCHROME-P-450 AND METALLOPORPHYRIN MODELS - EVIDENCE FOR ALLYLIC REARRANGEMENT [J].

GROVES, JT ;

SUBRAMANIAN, DV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (07) :2177-2181

[16] Macrocyclic hydroperoxocobalt(III) complex: Photochemistry, spectroscopy, and crystal structure [J].

Guzei, IA ;

Bakac, A .

INORGANIC CHEMISTRY, 2001, 40 (10) :2390-2393

[17] REDUCTIONS OF SUBSTITUTED 3,7-DIAZA-7-AZABICYCLO[3.3.1]NONAN-9-ONES AND 3-THIA-7-AZABICYCLO[3.3.1]NONAN-9-ONES WITH SODIUM-BOROHYDRIDE [J].

HALLER, R ;

ASHAUER, U .

ARCHIV DER PHARMAZIE, 1985, 318 (05) :405-410

[18] Iminodiacetate as a didentate ligand: base induced dealkylation [J].

Hartshorn, RM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (16) :3214-3218

[19] Aliphatic C-H bond oxygenation by the CoIIOOX species with the hindered hydrotris(pyrazolyl)borate ligand (X = Co(II), alkyl, H) [J].

Hikichi, S ;

Komatsuzaki, H ;

Akita, M ;

Moro-oka, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (19) :4699-4710

[20] Synthesis and reactivity of a (μ-1,1-hydroperoxo)(μ-hydroxo)dicopper(II) complex:: Ligand hydroxylation by a bridging hydroperoxo ligand [J].

Itoh, K ;

Hayashi, H ;

Furutachi, H ;

Matsumoto, T ;

Nagatomo, S ;

Tosha, T ;

Terada, S ;

Fujinami, S ;

Suzuki, M ;

Kitagawa, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (14) :5212-5223

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