Magnetic Pd-Fe3O4 Heterodimer Nanocrystals as Recoverable Catalysts for Ligand-Free Hiyama Cross-Coupling Reactions

被引：4

作者：

Lee, Woong-Sup ^{[1
]}

Byun, Sangmoon ^{[1
]}

Kwon, Jungmin ^{[1
]}

Kim, B. Moon ^{[1
]}

机构：

[1] Seoul Natl Univ, Dept Chem, Coll Nat Sci, Seoul 08826, South Korea

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2016年 / 37卷 / 12期

基金：

新加坡国家研究基金会;

关键词：

Hiyama cross-coupling reaction; Pd-Fe3O4; heterodimer nanocrystals; Magnetic separation; Heterogeneous catalysis; SUPPORTED PALLADIUM CATALYST; ARYL BROMIDES; HETEROGENEOUS CATALYST; ORGANIC HALIDES; SUZUKI-MIYAURA; FE3O4; NANOPARTICLES; HYDRAZINE HYDRATE; EFFICIENT; WATER; DERIVATIVES;

D O I：

10.1002/bkcs.11013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ligand-free Hiyama cross-coupling reaction was achieved through the use of Pd-Fe3O4 heterodimeric nanocrystals (1mol% in Pd) as recyclable catalysts. The nanocrystal catalysts exhibited good activities accommodating a variety of substrates including aryl bromides and iodides with substituents of varying electronic and steric properties. Furthermore, the nanocrystal catalyst could be conveniently recovered with the aid of an external magnet and recycled five times without the loss of catalytic activity to a considerable degree.

引用

页码：1992 / 1997

页数：6

共 53 条

[21] Polystyrene supported thiopseudourea Pd(II) complex: Applications for Sonogashira, Suzuki-Miyaura, Heck, Hiyama and Larock heteroannulation reactions [J].

Keesara, Srinivas ;

Parvathaneni, Saiprathima ;

Dussa, Govardhan ;

Mandapati, Mohan Rao .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 765 :31-38

[22] Efficient and Chemoselective Reduction of Olefins Catalyzed by Fe3O4 Nanoparticles using Hydrazine Hydrate [J].

Kim, Eunsuk ;

Kim, Seyoung ;

Kim, B. Moon .

BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2011, 32 (08) :3183-3186

[23] Fe3O4 Nanoparticles: A Conveniently Reusable Catalyst for the Reduction of Nitroarenes Using Hydrazine Hydrate [J].

Kim, Seyoung ;

Kim, Eunsuk ;

Kim, B. Moon .

CHEMISTRY-AN ASIAN JOURNAL, 2011, 6 (08) :1921-1925

[24] Recent applications of the Suzuki-Miyaura cross-coupling reaction in organic synthesis [J].

Kotha, S ;

Lahiri, K ;

Kashinath, D .

TETRAHEDRON, 2002, 58 (48) :9633-9695

[25] Synthesis, Characterization and Catalytic Applications of Palladium Nanoparticle-Cored Dendrimers Stabilized by Metal-Carbon Bonds [J].

Kumar, V. K. Ratheesh ;

Krishnakumar, Sreedevi ;

Gopidas, Karical R. .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2012, 2012 (18) :3447-3458

[26] Efficient Synthesis of Indole Derivatives via Tandem Cyclization Catalyzed by Magnetically Recoverable Palladium/Magnetite (Pd-Fe3O4) Nanocrystals [J].

Kwon, Jungmin ;

Chung, Jooyoung ;

Byun, Sangmoon ;

Kim, B. Moon .

ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 5 (04) :470-476

[27] Direct catalytic C-H arylation of imidazo[1,2-a]pyridine with aryl bromides using magnetically recyclable Pd-Fe3O4 nanoparticles [J].

Lee, Jaewoo ;

Chung, Jooyoung ;

Byun, Sang Moon ;

Kim, B. Moon ;

Lee, Chulbom .

TETRAHEDRON, 2013, 69 (27-28) :5660-5664

[28] Atropisomerism, biphenyls and the Suzuki coupling: peptide antibiotics [J].

Lloyd-Williams, P ;

Giralt, E .

CHEMICAL SOCIETY REVIEWS, 2001, 30 (03) :145-157

[29] Activity of boscalid, fenhexamid, fluazinam, fludioxonil, and vinclozolin on growth of Sclerotinia minor and S. sclerotiorum and development of lettuce drop [J].

Matheron, ME ;

Porchas, M .

PLANT DISEASE, 2004, 88 (06) :665-668

[30] Palladium-Catalyzed Hiyama Cross-Coupling of Aryltrifluorosilanes with Aryl and Heteroaryl Chlorides [J].

Molander, Gary A. ;

Iannazzo, Laura .

JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (21) :9182-9187

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