Cooperative intergrowth effect in LaMnO3, La2CuO4 and CuO three-phase system with broad active window for highly efficient NOx reduction

被引：8
作者：
Wu, Yaohui [1 ,2 ]
Liu, Xia [1 ]
Wei, Longqing [1 ]
Liu, Hao [1 ]
Ou, Xuemei [1 ]
Dong, Lihui [1 ]
Fan, Minguang [1 ]
Li, Bin [1 ]
机构：
[1] Guangxi Univ, Guangxi Key Lab Petrochem Resource Proc & Proc In, Sch Chem & Chem Engn, Nanning 530004, Peoples R China
[2] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China
来源：
FUEL | 2020年 / 278卷
基金：
中国国家自然科学基金;
关键词：
Three-phase intergrowth system; NO reduction; In situ DRIFTS; Wide active window; PEROVSKITE OXIDE CATALYSTS; PHYSICOCHEMICAL PROPERTIES; CO OXIDATION; TEMPERATURE; MN; DECOMPOSITION; TOPOCHEMISTRY; PERFORMANCE; CUO/CEO2; IRON;
D O I：
10.1016/j.fuel.2020.118266
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
The phase composition is tuned to analyze the influence of intergrowth and coexistence in LaMnO3, La2CuO4 and CuO three-phase system in NOx reduction. Among them, different phases of catalyst with LaMnO3 and La2CuO4 two-phase system play a role in the catalytic reaction at different temperatures, thereby maintaining excellent catalytic performance with broad active window from 275 to 1000 degrees C. In addition, this two-phase system is the catalytic system to perform well in all of the following aspects, with decent practicability, superior long-term catalytic ability, excellent cyclic catalytic ability, reliable water and sulfur resistance, low toxicity, low cost, high reserves, and strong stability in high temperature range. This catalytic system has great value in practical applications.
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页数：11
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  • [1] The surface chemistry of iron oxide nanocrystals: surface reduction of γ-Fe2O3 to Fe3O4 by redox-active catechol surface ligands
    Daniel, P.
    Shylin, S. I.
    Lu, H.
    Tahir, M. N.
    Panthoefer, M.
    Weidner, T.
    Moeller, A.
    Ksenofontova, V.
    Tremel, W.
    [J]. JOURNAL OF MATERIALS CHEMISTRY C, 2018, 6 (02) : 326 - 333
  • [2] Selective catalytic reduction of NOx by CO over bimetallic transition metals supported by multi-walled carbon nanotubes (MWCNT)
    Dasireddy, Venkata D. B. C.
    Likozar, Blaz
    [J]. CHEMICAL ENGINEERING JOURNAL, 2017, 326 : 886 - 900
  • [3] Influences of doping and thermal stability on the catalytic performance of CuO/Ce20M1Ox(M = Zr, Cr, Mn, Fe, Co, Sn) catalysts for NO reduction by CO
    Deng, Changshun
    Qian, Junning
    Yu, Chuxuan
    Yi, Yunan
    Zhang, Pan
    Li, Wei
    Dong, Lihui
    Li, Bin
    Fan, Minguang
    [J]. RSC ADVANCES, 2016, 6 (114): : 113630 - 113647
  • [4] The influence of Mn-doped CeO2 on the activity of CuO/CeO2 in CO oxidation and NO plus CO model reaction
    Deng, Changshun
    Huang, Qingqing
    Zhu, Xiying
    Hu, Qun
    Su, Wenli
    Qian, Junning
    Dong, Lihui
    Li, Bin
    Fan, Minguang
    Liang, Caiyuan
    [J]. APPLIED SURFACE SCIENCE, 2016, 389 : 1033 - 1049
  • [5] Interfacial Engineering of W2N/WC Heterostructures Derived from Solid-State Synthesis: A Highly Efficient Trifunctional Electrocatalyst for ORR, OER, and HER
    Diao, Jinxiang
    Qiu, Yu
    Liu, Shuangquan
    Wang, Weitao
    Chen, Kai
    Li, Hailong
    Yuan, Wenyu
    Qu, Yunteng
    Guo, Xiaohui
    [J]. ADVANCED MATERIALS, 2020, 32 (07)
  • [6] The effect of ceria content on the properties of Pd/CeO2/Al2O3 catalysts for steam reforming of methane
    Feio, L. S. F.
    Hori, C. E.
    Damyanova, S.
    Noronha, F. B.
    Cassinelli, W. H.
    Marques, C. M. P.
    Bueno, J. M. C.
    [J]. APPLIED CATALYSIS A-GENERAL, 2007, 316 (01) : 107 - 116
  • [7] The activity and characterization of CeO2-TiO2 catalysts prepared by the sol-gel method for selective catalytic reduction of NO with NH3
    Gao, Xiang
    Jiang, Ye
    Zhong, Yi
    Luo, Zhongyang
    Cen, Kefa
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2010, 174 (1-3) : 734 - 739
  • [8] Preparation, characterization and investigation of catalytic activity for NO plus CO reaction of LaMnO3 and LaFeO3 perovskites prepared via microemulsion method
    Giannakas, AE
    Ladavos, AK
    Pomonis, PJ
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2004, 49 (03) : 147 - 158
  • [9] On the mechanism of low-temperature water gas shift reaction on copper
    Gokhale, Amit A.
    Dumesic, James A.
    Mavrikakis, Manos
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (04) : 1402 - 1414
  • [10] Palladium-substituted lanthanum cuprates: Application to automotive exhaust purification
    Guilhaume, N
    Peter, SD
    Primet, M
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 1996, 10 (04) : 325 - 344
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