Chiral Quaternary Phosphonium Salts in Asymmetric Catalysis

被引：0

作者：

Yu Lide ^{[1
]}

Cui Hanfeng ^{[1
]}

Fan Hao ^{[1
]}

Ren Shuhui ^{[2
]}

Lin Yan ^{[1
]}

机构：

[1] Jiangxi Univ Tradit Chinese Med, Coll Pharm, Nanchang 330004, Peoples R China

[2] Jiangxi Univ Tradit Chinese Med, Coll Clin Med, Nanchang 330004, Peoples R China

来源：

PROGRESS IN CHEMISTRY | 2013年 / 25卷 / 05期

关键词：

chiral phase-tranfer catalysis; chiral quaternary phosphonium salts; asymmetric catalysis; PHASE-TRANSFER CATALYSTS; DIRECT HENRY REACTION; HYDROGEN-BONDING SITE; MANNICH-TYPE REACTION; ALPHA-AMINO-ACIDS; BETA-KETO-ESTERS; ARYLAMINOPHOSPHONIUM BARFATES; ENANTIOSELECTIVE ALKYLATION; TETRAAMINOPHOSPHONIUM SALTS; MICHAEL ADDITION;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral phase-tranfer catalysis plays an important role in modern asymmetric synthesis and organic synthesis chemistry. This review focuses on the progress of chiral quaternary phosphonium salts as phase-transfer catalysts reported in recent years, and their application in asymmetric catalytic reactions, including Henry reaction, hydrophosphonylation reaction, alkylation reaction, Michael addition reaction, Mannich reaction, aldol reaction, protonation reaction and amination reaction. Steric and electrical effects of these catalysts are emphasized, future prospects for development of chiral quaternary phosphonium salts are also described in this article.

引用

页码：744 / 751

页数：8

共 46 条

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