Synthesis and Applications of Perfunctionalized Boron Clusters

被引：127

作者：

Axtell, Jonathan C. ^{[1
]}

Saleh, Liban M. A. ^{[1
]}

Qian, Elaine A. ^{[1
,2
,3
]}

Wixtrom, Alex I. ^{[1
]}

Spokoyny, Alexander M. ^{[1
,3
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, 607 Charles E Young Dr East, Los Angeles, CA 90095 USA

[2] Univ Calif Los Angeles, Dept Bioengn, 420 Westwood Plaza, Los Angeles, CA 90095 USA

[3] Univ Calif Los Angeles, Calif NanoSyst Inst, 570 Westwood Plaza, Los Angeles, CA 90095 USA

来源：

INORGANIC CHEMISTRY | 2018年 / 57卷 / 05期

关键词：

NEUTRON-CAPTURE THERAPY; CLOSO-HALOGENOHYDROHEXABORATES XNB6H6-N2; FRAMEWORK ELECTRON CLUSTERS; NORMAL-COORDINATE ANALYSIS; C BOND-CLEAVAGE; X = CL; CRYSTAL-STRUCTURES; VIBRATIONAL-SPECTRA; MAGNETIC-RESONANCE; DELIVERY VEHICLES;

D O I：

10.1021/acs.inorgchem.7b02912

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This Viewpoint describes major advances pertaining to perfunctionalized boron clusters in synthesis and their respective applications. The first portion of this work highlights key synthetic methods, allowing one to access a wide range of polyhedral boranes (B-4 and B-6-B-12 cluster cores) that contain exhaustively functionalized vertices. The second portion of this Viewpoint showcases the historical developments in using these molecules for applications ranging from materials science to medicine. Last, we suggest potential new directions for these clusters as they apply to both synthetic methods and applications.

引用

收藏

页码：2333 / 2350

页数：18

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