Synthesis and Applications of Perfunctionalized Boron Clusters

被引：123

作者：

Axtell, Jonathan C. ^{[1
]}

Saleh, Liban M. A. ^{[1
]}

Qian, Elaine A. ^{[1
,2
,3
]}

Wixtrom, Alex I. ^{[1
]}

Spokoyny, Alexander M. ^{[1
,3
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, 607 Charles E Young Dr East, Los Angeles, CA 90095 USA

[2] Univ Calif Los Angeles, Dept Bioengn, 420 Westwood Plaza, Los Angeles, CA 90095 USA

[3] Univ Calif Los Angeles, Calif NanoSyst Inst, 570 Westwood Plaza, Los Angeles, CA 90095 USA

来源：

INORGANIC CHEMISTRY | 2018年 / 57卷 / 05期

关键词：

NEUTRON-CAPTURE THERAPY; CLOSO-HALOGENOHYDROHEXABORATES XNB6H6-N2; FRAMEWORK ELECTRON CLUSTERS; NORMAL-COORDINATE ANALYSIS; C BOND-CLEAVAGE; X = CL; CRYSTAL-STRUCTURES; VIBRATIONAL-SPECTRA; MAGNETIC-RESONANCE; DELIVERY VEHICLES;

D O I：

10.1021/acs.inorgchem.7b02912

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This Viewpoint describes major advances pertaining to perfunctionalized boron clusters in synthesis and their respective applications. The first portion of this work highlights key synthetic methods, allowing one to access a wide range of polyhedral boranes (B-4 and B-6-B-12 cluster cores) that contain exhaustively functionalized vertices. The second portion of this Viewpoint showcases the historical developments in using these molecules for applications ranging from materials science to medicine. Last, we suggest potential new directions for these clusters as they apply to both synthetic methods and applications.

引用

页码：2333 / 2350

页数：18

共 179 条

[1] Arata K., 2009, METAL OXIDE CATALYSI
[2] The bioinorganic and medicinal chemistry of carboranes: from new drug discovery to molecular imaging and therapy
Armstrong, Andrea F.
Valliant, John F.
[J]. DALTON TRANSACTIONS, 2007, (38) : 4240 - 4251
[3] ASBURY A K, 1972, Journal of Neuropathology and Experimental Neurology, V31, P278, DOI 10.1097/00005072-197204000-00005
[4] THE CRYSTAL AND MOLECULAR STRUCTURE OF B4CL4
ATOJI, M
LIPSCOMB, WN
[J]. ACTA CRYSTALLOGRAPHICA, 1953, 6 (06): : 547 - 550
[5] Controlling Structure and Porosity in Catalytic Nanoparticle Superlattices with DNA
Auyeung, Evelyn
Morris, William
Mondloch, Joseph E.
Hupp, Joseph T.
Farha, Omar K.
Mirkin, Chad A.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (04) : 1658 - 1662
[6] Superacidity of Boron Acids H2(B12X12) (X = Cl, Br)
Avelar, Amy
Tham, Fook S.
Reed, Christopher A.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (19) : 3491 - 3493
[7] Metal-Free Peralkylation of the closo-Hexaborate Anion
Axtell, Jonathan C.
Kirlikovali, Kent O.
Jung, Dahee
Dziedzic, Rafal M.
Rheingold, Arnold L.
Spokoyny, Alexander M.
[J]. ORGANOMETALLICS, 2017, 36 (06) : 1204 - 1210
[8] Boron neutron capture therapy of cancer: Current status and future prospects
Barth, RF
Coderre, JA
Vicente, MGH
Blue, TE
[J]. CLINICAL CANCER RESEARCH, 2005, 11 (11) : 3987 - 4002
[9] BARTH RF, 1992, CANCER-AM CANCER SOC, V70, P2995
[10] Improving the Solubility of Halogenated 1-Ammonio-closo-dodecaborate Anions
Bertocco, Philipp
Derendorf, Janis
Jenne, Carsten
Kirsch, Christoph
[J]. INORGANIC CHEMISTRY, 2017, 56 (06) : 3459 - 3466

← 1 2 3 4 5 6 7 8 9 10 →