Structural characterization of amorphous carbon nitride thin films prepared by pulsed laser deposition

被引:1
作者
Aoi, Y [1 ]
Sakurada, K [1 ]
Ono, K [1 ]
Kamijo, E [1 ]
机构
[1] Ryukoku Univ, Fac Sci & Technol, Otsu, Shiga 5202194, Japan
来源
EURO CERAMICS VII, PT 1-3 | 2002年 / 206-2卷
关键词
carbon nitride; thin film; structural characterization; pulsed laser deposition;
D O I
10.4028/www.scientific.net/KEM.206-213.531
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Amorphous carbon nitride thin films were deposited by pulsed laser deposition in nitrogen atmosphere and under nitrogen radical beam irradiation. The deposited films were characterized by scanning electron microscope, x-ray photoelectron spectroscopy (XPS), Raman scattering and Fourier transform infrared spectroscopy (FTIR). The maximum N/C ratio of the deposited film was 0.24 in this experimental. Structural characterization by XPS indicated that the nitrogen atoms in the film were mainly bonded in N-sp(3)C and N-sp(2)C configurations. The ratio of N-sp(3)C slightly increased and the ratio of N-sp(2)C decreased with increasing NIC atomic ratio of the deposited film. FTIR and Raman spectra indicated that N-spC are small as compared with N-sp(3)C and N-sp(2)C.
引用
收藏
页码:531 / 534
页数:4
相关论文
共 9 条
[1]  
Chrisey D. B., 1994, PULSED LASER DEPOSIT
[2]   USE OF RAMAN-SCATTERING TO INVESTIGATE DISORDER AND CRYSTALLITE FORMATION IN AS-DEPOSITED AND ANNEALED CARBON-FILMS [J].
DILLON, RO ;
WOOLLAM, JA ;
KATKANANT, V .
PHYSICAL REVIEW B, 1984, 29 (06) :3482-3489
[3]   Role of nitrogen in the formation of hard and elastic CNx thin films by reactive magnetron sputtering [J].
Hellgren, N ;
Johansson, MP ;
Broitman, E ;
Hultman, L ;
Sundgren, JE .
PHYSICAL REVIEW B, 1999, 59 (07) :5162-5169
[4]   Thermal stability and relaxation in diamond-like-carbon.: A Raman study of films with different sp3 fractions (ta-C to a-C) [J].
Kalish, R ;
Lifshitz, Y ;
Nugent, K ;
Prawer, S .
APPLIED PHYSICS LETTERS, 1999, 74 (20) :2936-2938
[5]   STRUCTURAL-PROPERTIES AND ELECTRONIC-STRUCTURE OF LOW-COMPRESSIBILITY MATERIALS - BETA-SI3N4 AND HYPOTHETICAL BETA-C3N4 [J].
LIU, AY ;
COHEN, ML .
PHYSICAL REVIEW B, 1990, 41 (15) :10727-10734
[6]   PREDICTION OF NEW LOW COMPRESSIBILITY SOLIDS [J].
LIU, AY ;
COHEN, ML .
SCIENCE, 1989, 245 (4920) :841-842
[7]   CARBON NITRIDE DEPOSITED USING ENERGETIC SPECIES - A 2-PHASE SYSTEM [J].
MARTON, D ;
BOYD, KJ ;
ALBAYATI, AH ;
TODOROV, SS ;
RABALAIS, JW .
PHYSICAL REVIEW LETTERS, 1994, 73 (01) :118-121
[8]   A review of the preparation of carbon nitride films [J].
Muhl, S ;
Méndez, JM .
DIAMOND AND RELATED MATERIALS, 1999, 8 (10) :1809-1830
[9]   Raman spectroscopy on amorphous carbon films [J].
Schwan, J ;
Ulrich, S ;
Batori, V ;
Ehrhardt, H ;
Silva, SRP .
JOURNAL OF APPLIED PHYSICS, 1996, 80 (01) :440-447