Role of Ge switch in phase transition:: Approach using atomically controlled GeTe/Sb2Te3 superlattice

被引:63
作者
Tominaga, Juniji [1 ]
Fons, Paul [1 ]
Kolobov, Alexander [1 ]
Shima, Takayuki [1 ]
Chong, Tow Chong [2 ]
Zhao, Rong [2 ]
Lee, Hock Koon [2 ]
Shi, Luping [2 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, CAN FOR, Tsukuba, Ibaraki 3058562, Japan
[2] Data Storage Inst, Singapore 117608, Singapore
关键词
GeSbTe alloy; crystal; amorphous; phase transition; ab-initio simulation; refractive index;
D O I
10.1143/JJAP.47.5763
中图分类号
O59 [应用物理学];
学科分类号
摘要
Germanium-antimony-tellurite (GST) is a very attractive material not only for rewritable optical media but also for realizing solid state devices. Recently, the study of the switching mechanism between the amorphous and crystal states has actively been carried out experimentally and theoretically. Now, the role of the flip-flop transition of a Ge atom in a distorted simple-cubic unit cell is the center of discussion. Turning our viewpoint towards a much wider region beyond a unit cell, we. can understand that GeSbTe consists of two units: one is a Sb2Te3 layer and the other is a Ge2Te2 layer. On the based of this simple model, we fabricated the superlattice of GST alloys and estimated their thermal properties by differential scanning calorimetry (DSC). In this paper, we discuss the proof of the Ge switch on the basis of thermo-histories.
引用
收藏
页码:5763 / 5766
页数:4
相关论文
共 15 条
[1]   GROUND-STATE OF THE ELECTRON-GAS BY A STOCHASTIC METHOD [J].
CEPERLEY, DM ;
ALDER, BJ .
PHYSICAL REVIEW LETTERS, 1980, 45 (07) :566-569
[2]   Phase change random access memory cell with superlattice-like structure [J].
Chong, TC ;
Shi, LP ;
Zhao, R ;
Tan, PK ;
Li, JM ;
Lee, HK ;
Miao, XS ;
Du, AY ;
Tung, CH .
APPLIED PHYSICS LETTERS, 2006, 88 (12)
[3]   Understanding the phase-change mechanism of rewritable optical media [J].
Kolobov, AV ;
Fons, P ;
Frenkel, AI ;
Ankudinov, AL ;
Tominaga, J ;
Uruga, T .
NATURE MATERIALS, 2004, 3 (10) :703-708
[4]   Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set [J].
Kresse, G ;
Furthmuller, J .
PHYSICAL REVIEW B, 1996, 54 (16) :11169-11186
[5]  
Martin R.M., 2004, Electronic Structure
[6]  
Milman V, 2000, INT J QUANTUM CHEM, V77, P895, DOI 10.1002/(SICI)1097-461X(2000)77:5<895::AID-QUA10>3.0.CO
[7]  
2-C
[8]  
MONKHORST HJ, 1976, PHYS REV B, V13, P1588
[9]   ITERATIVE MINIMIZATION TECHNIQUES FOR ABINITIO TOTAL-ENERGY CALCULATIONS - MOLECULAR-DYNAMICS AND CONJUGATE GRADIENTS [J].
PAYNE, MC ;
TETER, MP ;
ALLAN, DC ;
ARIAS, TA ;
JOANNOPOULOS, JD .
REVIEWS OF MODERN PHYSICS, 1992, 64 (04) :1045-1097
[10]  
PREDEW JP, 1981, PHYS REV B, V23, P5305