Olefin metathesis over supported rhenium oxide catalysts

被引:215
作者
Mol, JC [1 ]
机构
[1] Univ Amsterdam, Fac Chem, Inst Mol Chem, NL-1018 WV Amsterdam, Netherlands
关键词
alumina; silica-alumina; metathesis catalysts; olefin metathesis; rhenium oxide;
D O I
10.1016/S0920-5861(99)00051-6
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Supported rhenium oxide has attracted much attention as solid catalyst for the olefin metathesis reaction because of practical applications. These catalysts are composed of rhenium oxide dispersed over a high surface-area support, such as alumina or silica-alumina. They have a high activity and high selectivity at temperatures of 0-100 degrees C, while they bring about the metathesis of functionally substituted olefins when promoted with a suitable organometallic compound. The interaction of rhenium oxide with the support has been studied by a number of characterisation techniques, resulting in a detailed picture of the structure of the supported rhenium oxide. In this paper an overview is given of the current knowledge about rhenium-based metathesis catalysts, in particular the industrially used Re2O7/Al2O3 catalyst. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:289 / 299
页数:11
相关论文
共 77 条
[61]   STRUCTURAL DETERMINATION OF SURFACE RHENIUM OXIDE ON VARIOUS OXIDE SUPPORTS (AL2O3, ZRO2, TIO2 AND SIO2) [J].
VUURMAN, MA ;
STUFKENS, DJ ;
OSKAM, A ;
WACHS, IE .
JOURNAL OF MOLECULAR CATALYSIS, 1992, 76 (1-3) :263-285
[62]   INSITU RAMAN-SPECTROSCOPY OF ALUMINA-SUPPORTED METAL-OXIDE CATALYSTS [J].
VUURMAN, MA ;
WACHS, IE .
JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (12) :5008-5016
[63]  
Wachs I. E., 1992, CHARACTERIZATION CAT
[64]  
Wang L., 1983, J CATAL, V82, P177
[65]   RAMAN-SPECTROSCOPIC STUDIES OF THE EFFECTS OF TIN PROMOTION ON A RHENIUM ALUMINA DISMUTATION CATALYST [J].
WILLIAMS, KPJ ;
HARRISON, K .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (09) :1603-1606
[66]  
XU XD, 1985, J MOL CATAL, V28, P133
[67]  
XU XD, 1986, J MOL CATAL, V36, P47
[68]  
XU XD, 1986, J CHEM SOC FARAD T 1, V82, P1945
[69]  
XU XD, 1985, J CHEM SOC CHEM COMM, P273
[70]  
XU XD, 1985, J CHEM SOC CHEM COMM, P631