Novel Bi2S3-sensitized BiOCl with highly visible light photocatalytic activity for the removal of rhodamine B

被引:179
作者
Cao, Jing [1 ]
Xu, Benyan [1 ]
Lin, Haili [1 ]
Luo, Bangde [1 ]
Chen, Shifu [1 ]
机构
[1] Huaibei Normal Univ, Coll Chem & Mat Sci, Huaibei 235000, Anhui, Peoples R China
关键词
Bi2S3/BiOCl; Heterostructure; Photocatalysis; Photosensitization; Rhodamine B; MAGNETIC PHOTOCATALYST; METHYLENE-BLUE; DEGRADATION; ARCHITECTURES; IRRADIATION; OXIDATION; STRATEGY; WATER; CORE;
D O I
10.1016/j.catcom.2012.05.025
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Bi2S3-sensitized BiOCl photocatalyst (Bi2S3/BiOCl) was synthesized through a facile and economical ion exchange method between BiOCl and thioacetamide. XRD, XPS, Raman, FT-IR, DRS, SEM, EDS, TEM, HRTEM, SAED and BET were employed to study the properties of Bi2S3/BiOCl heterostructure. To evaluate the photocatalytic activity of Bi2S3/BiOCl, rhodamine B (RhB) was introduced as a model contaminant and 98.0% of RhB could be degraded within 120 min under visible light irradiation (lambda > 400 nm), which was much higher than that of single BiOCl, Bi2S3 and TiO2 (P25). Moreover, a detailed mechanism was also proposed to illustrate enhanced photocatalytic activity. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:204 / 208
页数:5
相关论文
共 32 条
[1]   Adsorption and catalytic properties of SiO2/Bi2S3 nanocomposites on the methylene blue photodecolorization process [J].
Albuquerque, Rita ;
Neves, Marcia C. ;
Mendonca, Maria H. ;
Trindade, Tito ;
Monteiro, Olinda C. .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 328 (1-3) :107-113
[2]   Degradation of commercial reactive dyestuffs by heterogenous and homogenous advanced oxidation processes: a comparative study [J].
Arslan, I ;
Balcioglu, IA .
DYES AND PIGMENTS, 1999, 43 (02) :95-108
[3]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[4]   Bi2S3/TiO2 and CdS/TiO2 heterojunctions as an available configuration for photocatalytic degradation of organic pollutant [J].
Bessekhouad, Y ;
Robert, D ;
Weber, J .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 163 (03) :569-580
[5]   Novel BiOI/BiOBr heterojunction photocatalysts with enhanced visible light photocatalytic properties [J].
Cao, Jing ;
Xu, Benyan ;
Luo, Bangde ;
Lin, Haili ;
Chen, Shifu .
CATALYSIS COMMUNICATIONS, 2011, 13 (01) :63-68
[6]   Heterojunctioned BiOCl/Bi2O3, a new visible light photocatalyst [J].
Chai, Seung Yong ;
Kim, Yong Joo ;
Jung, Myong Hak ;
Chakraborty, Ashok Kumar ;
Jung, Dongwoon ;
Lee, Wan In .
JOURNAL OF CATALYSIS, 2009, 262 (01) :144-149
[7]   Enhancement of photocatalytic activity over NaBiO3/BiOCl composite prepared by an in situ formation strategy [J].
Chang, Xiaofeng ;
Yu, Gang ;
Huang, Jun ;
Li, Zheng ;
Zhu, Shufeng ;
Yu, Pingfeng ;
Cheng, Cheng ;
Deng, Shubo ;
Ji, Guangbin .
CATALYSIS TODAY, 2010, 153 (3-4) :193-199
[8]   A controlled anion exchange strategy to synthesize Bi2S3 nanocrystals/BiOCl hybrid architectures with efficient visible light photoactivity [J].
Cheng, Hefeng ;
Huang, Baibiao ;
Qin, Xiaoyan ;
Zhang, Xiaoyang ;
Dai, Ying .
CHEMICAL COMMUNICATIONS, 2012, 48 (01) :97-99
[9]   SOLID-STATE VIBRATIONAL SPECTROSCOPY .3. INFRARED AND RAMAN-SPECTRA OF BISMUTH(III) OXIDE HALIDES [J].
DAVIES, JED .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1973, 35 (05) :1531-1534
[10]   Regulation of osteogenic differentiation during skeletal development [J].
Deng, Zhong-Liang ;
Sharff, Katie A. ;
Tang, Ni ;
Song, Wen-Xin ;
Luo, Jinyong ;
Luo, Xiaoji ;
Chen, Jin ;
Bennett, Erwin ;
Reid, Russell ;
Manning, David ;
Xue, Anita ;
Montag, Anthony G. ;
Luu, Hue H. ;
Haydon, Rex C. ;
He, Tong-Chuan .
FRONTIERS IN BIOSCIENCE-LANDMARK, 2008, 13 :2001-2021