Amine-directed structural studies of four zinc metal-organic frameworks based on a novel phosphonocarboxylate ligand

被引：10
作者：
Dan, Wenyan [1 ]
Liu, Xiaofeng [1 ]
Deng, Mingli [1 ]
Ling, Yun [1 ]
Chen, Zhenxia [1 ]
Zhou, Yaming [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 37卷
关键词：
Metal phosphonocarboxylate; Synthesis; Topology; Luminescence; LUMINESCENT PROPERTIES; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; PHOSPHONATE; ADSORPTION; TRANSFORMATION; HYDROGEN; STORAGE; SERIES;
D O I：
10.1016/j.inoche.2013.09.030
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel phosphonocarboxylic ligand, 4'-phosphonobiphenyl-3,5-dicarboxylic acid (H(4)pbpdc), was synthesized to construct 4 zinc compounds, namely, {(Zn-3(pbpdc)(2)center dot 2R}(n) (R = C5H12N for 1. C4H10N for 2 and C6H16N for 3) and ([Zn(2)pbpdc]center dot C6H18N3}(n) (4), which were characterized by X-ray crystallography, elemental analysis, FTIR and TG. Structures 1 similar to 3 have the same 3-dimensional (3-D) frameworks with point symbol of {4.6.7(3).8)(2) {4(2).6.7(2).8}(2){4(2).6(2).7.8}(2){4(2).6(2).7(2)}. Structure 4 is constructed from a 6-connected metallic cluster and 3-connected phosphonocarboxylic building units resulting in a topology of flu-3,6-C2/c. The luminescent properties of compounds 1 similar to 4 and organic ligand were studied. (C) 2013 Elsevier B.V. All rights reserved.
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页码：93 / 96
页数：4
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