Clean and efficient oxidation of homoallylic and homopropargylic alcohols into β,γ-unsaturated aldehydes by the Dess-Martin periodinane

被引：0
作者：
Wavrin, L [1 ]
Viala, J [1 ]
机构：
[1] Fac Sci & Tech St Jerome, UMR CNRS 6516, Lab ReSo, F-13397 Marseille 20, France
来源：
SYNTHESIS-STUTTGART | 2002年 / 03期
关键词：
beta; gamma-ethylenic aldehyde; gamma-acetylenic aldehyde; oxidation; Dess-Martin periodinane; DMP;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We describe the first efficient oxidation of homoallylic and homopropargylic alcohols to the corresponding very sensitive and unstable beta,gamma-unsaturated aldehydes by using the Dess-Martin periodinane with a new neutral and anhydrous extraction protocol.
引用
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页码：326 / 330
页数：5
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