First regioselective cyclometalation reactions of cobalt in arylketones: C-H versus C-F activation

被引：35

作者：

Camadanli, Sebnem ^{[1
,2
]}

Beck, Robert ^{[1
]}

Floerke, Ulrich ^{[3
]}

Klein, Hans-Friedrich ^{[1
]}

机构：

[1] Tech Univ Darmstadt, Eduard Zintl Inst, D-64287 Darmstadt, Germany

[2] Leibniz Inst Surface Modificat, D-04318 Leipzig, Germany

[3] Univ Gesamthsch Paderborn, D-33098 Paderborn, Germany

来源：

DALTON TRANSACTIONS | 2008年 / 42期

关键词：

D O I：

10.1039/b813419g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Phenyl ketones react smoothly under mild conditions with low valent cobalt(I) adducts to form new and stable five-membered cobaltacycles via C-H and C-F activation.

引用

页码：5701 / 5704

页数：4

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