A Simple Chemical Route toward Monodisperse Iron Carbide Nanoparticles Displaying Tunable Magnetic and Unprecedented Hyperthermia Properties

被引:167
|
作者
Meffre, Anca [1 ]
Mehdaoui, Boubker [1 ]
Kelsen, Vinciane [1 ]
Fazzini, Pier Francesco [1 ]
Carrey, Julian [1 ]
Lachaize, Sebastien [1 ]
Respaud, Marc [1 ]
Chaudret, Bruno [1 ]
机构
[1] Univ Toulouse, INSA, Lab Phys & Chim Nano Objets, F-31077 Toulouse, France
关键词
Magnetic nanoparticles; iron carbides; iron; core/shell; hyperthermia; organometallic chemistry; SUPERLATTICES; STABILIZATION; SIZE; FE;
D O I
10.1021/nl302160d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report a tunable organometallic synthesis of monodisperse iron carbide and core/shell iron/iron carbide nanoparticles displaying a high magnetization and good air-stability. This process based on the decomposition of Fe(CO)(5) on Fe(0) seed:, allows the control of the amount of carbon diffused and therefore the tuning of nanoparticles magnetic anisotropy. This results in unprecedented hyperthermia properties at moderate magnetic fields, in the range of medical treatments.
引用
收藏
页码:4722 / 4728
页数:7
相关论文
共 23 条
  • [1] Chemical Synthesis and Magnetic Properties of Monodisperse Nickel Ferrite Nanoparticles for Biomedical Applications
    Lasheras, Xabier
    Insausti, Maite
    Gil de Muro, Izaskun
    Garaio, Eneko
    Plazaola, Fernando
    Moros, Maria
    De Matteis, Laura
    de la Fuente, Jesus M.
    Lezama, Luis
    JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (06) : 3492 - 3500
  • [2] Chemical synthesis and magnetic properties of monodisperse cobalt ferrite nanoparticles
    Mahhouti, Z.
    El Moussaoui, H.
    Mahfoud, T.
    Hamedoun, M.
    El Marssi, M.
    Lahmar, A.
    El Kenz, A.
    Benyoussef, A.
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2019, 30 (16) : 14913 - 14922
  • [3] Correlating Magneto-Structural Properties to Hyperthermia Performance of Highly Monodisperse Iron Oxide Nanoparticles Prepared by a Seeded-Growth Route
    Levy, Michael
    Quarta, Alessandra
    Espinosa, Ana
    Figuerola, Albert
    Wilhelm, Claire
    Garcia-Hernandez, Mar
    Genovese, Alessandro
    Falqui, Andrea
    Alloyeau, Damien
    Buonsanti, Raffaella
    Davide Cozzoli, Pantaleo
    Angel Garcia, Miguel
    Gazeau, Florence
    Pellegrino, Teresa
    CHEMISTRY OF MATERIALS, 2011, 23 (18) : 4170 - 4180
  • [4] Structural effects on the magnetic hyperthermia properties of iron oxide nanoparticles
    Abenojar, Eric C.
    Wickramasinghe, Sameera
    Bas-Concepcion, Jesbaniris
    Samia, Anna Cristina S.
    PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL, 2016, 26 (05) : 440 - 448
  • [5] Iron nanoparticles with tunable tetragonal structure and magnetic properties
    Liu, Jinming
    Schliep, Karl
    He, Shi-Hai
    Ma, Bin
    Jing, Ying
    Flannigan, David J.
    Wang, Jian-Ping
    PHYSICAL REVIEW MATERIALS, 2018, 2 (05):
  • [6] Biocompatible Magnetic Fluids of Co-Doped Iron Oxide Nanoparticles with Tunable Magnetic Properties
    Dutz, Silvio
    Buske, Norbert
    Landers, Joachim
    Graefe, Christine
    Wende, Heiko
    Clement, Joachim H.
    NANOMATERIALS, 2020, 10 (06)
  • [7] Influence of clustering on the magnetic properties and hyperthermia performance of iron oxide nanoparticles
    Bender, P.
    Fock, J.
    Hansen, M. F.
    Bogart, K.
    Southern, P.
    Ludwig, F.
    Wiekhorst, F.
    Szczerba, W.
    Zeng, L. J.
    Heinke, D.
    Gehrke, N.
    Diaz, M. T. Fernandez
    Gonzalez-Alonso, D.
    Espeso, J., I
    Rodriguez Fernandez, J.
    Johansson, C.
    NANOTECHNOLOGY, 2018, 29 (42)
  • [8] Synthesis, characterization and magnetic hyperthermia properties of nearly monodisperse CoFe2O4 nanoparticles
    Manohar, Ala
    Geleta, Dereje Degefa
    Krishnamoorthi, Chintagumpala
    Lee, Joonho
    CERAMICS INTERNATIONAL, 2020, 46 (18) : 28035 - 28041
  • [9] Enhancing the magnetic properties of superparamagnetic iron oxide nanoparticles using hydrothermal treatment for magnetic hyperthermia application
    Martins, Carla
    Rolo, Catarina
    Cacho, Vanessa R. G.
    Pereira, Laura C. J.
    Borges, Joao Paulo
    Silva, Jorge Carvalho
    Vieira, Tania
    Soares, Paula I. P.
    MATERIALS ADVANCES, 2025, 6 (05): : 1726 - 1743
  • [10] Magnetic properties of iron oxide nanoparticles prepared by seeded-growth route
    Espinosa, A.
    Munoz-Noval, A.
    Garcia-Hernandez, M.
    Serrano, A.
    Jimenez de la Morena, J.
    Figuerola, A.
    Quarta, A.
    Pellegrino, T.
    Wilhelm, C.
    Garcia, M. A.
    JOURNAL OF NANOPARTICLE RESEARCH, 2013, 15 (04)