Enhanced photoelectrochemical performance of TiO2 nanotube arrays with coexisted Pt nanoparticles and Co-Pi cocatalysts

被引:18
作者
Li, Yanfang [1 ]
Cao, Chang [1 ]
Xie, Xinxin [1 ]
Zhang, Li [1 ]
Lin, Shiwei [1 ]
机构
[1] Hainan Univ, Coll Mat & Chem Engn, Key Lab, Minist Educ Adv Mat Trop Isl Resources, Haikou 570228, Hainan, Peoples R China
基金
中国国家自然科学基金;
关键词
TiO2 Nanotube arrays; Cocatalysts; Photoelectrochemical performance; Water splitting; HYDROGEN GENERATION; OXYGEN EVOLUTION; WATER; PHOTOCATALYSIS; FABRICATION; EFFICIENCY; COMPOSITE; OXIDATION; CATALYST;
D O I
10.1016/j.apsusc.2017.12.062
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Highly-ordered TiO2 nanotube arrays (TNTAs) were prepared by electrochemical anodization. Cobalt-phosphate (Co-Pi) film fabricated by electrodeposition and Pt nanoparticles (Pt NPs) fabricated by photochemical reduction were decorated onto TNTAs to enhance the photoelectrochemical (PEC) performance together. The photocurrent density of the TNTAs/Co-Pi/Pt photoelectrode could reach 0.185 mA/cm(2) at 1.23 V versus reversible hydrogen electrode under UV lamp illumination (1 mW/cm(2)), which is 2.65 times compared to that of the pure TNTAs photoelectrode. Electrochemistry impedance spectroscopy and Mott-Schottky analysis were conducted to explore the reasons for the enhancement of the PEC performance. Pt NPs could promote the reduction of Co(IV)-oxo intermediate to Co(II) or Co(III) which facilitated the charge transfer in the PEC performance. The result provides a promising guideline to design a simple and efficient photoelectrode for the PEC water-splitting system. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:337 / 344
页数:8
相关论文
共 42 条
[1]   Solar Water Splitting by TiO2/CdS/Co-Pi Nanowire Array Photoanode Enhanced with Co-Pi as Hole Transfer Relay and CdS as Light Absorber [J].
Ai, Guanjie ;
Li, Hongxing ;
Liu, Shaopei ;
Mo, Rong ;
Zhong, Jianxin .
ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (35) :5706-5713
[2]   Cobalt phosphate modified TiO2 nanowire arrays as co-catalysts for solar water splitting [J].
Ai, Guanjie ;
Mo, Rong ;
Li, Hongxing ;
Zhong, Jianxin .
NANOSCALE, 2015, 7 (15) :6722-6728
[3]   Vertically Oriented Ti-Pd Mixed Oxynitride Nanotube Arrays for Enhanced Photoelectrochemical Water Splitting [J].
Allam, Nageh K. ;
Poncheri, Adam J. ;
El-Sayed, Mostafa A. .
ACS NANO, 2011, 5 (06) :5056-5066
[4]   Synthesis and Enhanced Visible-Light Photoelectrocatalytic Activity of p-n Junction BiOI/TiO2 Nanotube Arrays [J].
Dai, Gaopeng ;
Yu, Jiaguo ;
Liu, Gang .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (15) :7339-7346
[5]   Enhanced photocatalytic H2 production on CdS nanorod using cobalt-phosphate as oxidation cocatalyst [J].
Di, Tingmin ;
Zhu, Bicheng ;
Zhang, Jun ;
Cheng, Bei ;
Yu, Jiaguo .
APPLIED SURFACE SCIENCE, 2016, 389 :775-782
[6]   ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].
FUJISHIMA, A ;
HONDA, K .
NATURE, 1972, 238 (5358) :37-+
[7]   TiO2 photocatalysis and related surface phenomena [J].
Fujishima, Akira ;
Zhang, Xintong ;
Tryk, Donald A. .
SURFACE SCIENCE REPORTS, 2008, 63 (12) :515-582
[8]   A simple preparation method and characterization of B and N co-doped TiO2 nanotube arrays with enhanced photoelectrochemical performance [J].
Georgieva, J. ;
Valova, E. ;
Armyanov, S. ;
Tatchev, D. ;
Sotiropoulos, S. ;
Avramova, I. ;
Dimitrova, N. ;
Hubin, A. ;
Steenhaut, O. .
APPLIED SURFACE SCIENCE, 2017, 413 :284-291
[9]   A surface science perspective on TiO2 photocatalysis [J].
Henderson, Michael A. .
SURFACE SCIENCE REPORTS, 2011, 66 (6-7) :185-297
[10]   TiO2 nanotube/Ag-AgBr three-component nanojunction for efficient photoconversion [J].
Hou, Yang ;
Li, Xinyong ;
Zhao, Qidong ;
Quan, Xie ;
Chen, Guohua .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (44) :18067-18076