Liquid-phase dehydration of 1-phenylethanol to styrene over sulfonated D-glucose catalyst

被引：22

作者：

Hasan, Zubair ^{[1
,2
]}

Hwang, Jin-Soo ^{[3
]}

Jhung, Sung Hwa ^{[1
,2
]}

机构：

[1] Kyungpook Natl Univ, Dept Chem, Taegu 702701, South Korea

[2] Kyungpook Natl Univ, Green Nano Mat Res Ctr, Taegu 702701, South Korea

[3] Korea Res Inst Chem Technol, Biorefinerary Res Ctr, Taejon 305600, South Korea

来源：

CATALYSIS COMMUNICATIONS | 2012年 / 26卷

关键词：

Dehydration; Phenylethanol; Styrene; Carbon-based solid acid catalysts; Sulfonation; SOLID-ACID CATALYST; CARBONACEOUS MATERIALS; REACTIVE DISTILLATION; METHANOL CONVERSION; PHENYL-ETHANOL; DEACTIVATION; SAPO-34; ETHER;

D O I：

10.1016/j.catcom.2012.05.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dehydration of 1-phenylethanol to produce styrene has been studied in liquid phase without any solvent with carbon-based solid acid catalysts prepared in one step from renewable resources like D-glucose for the first time. The carbon-based catalyst shows higher styrene selectivity and lower activation energy than other solid acid catalysts that have been used so far, demonstrating that a carbon-based catalyst is very effective in producing styrene from 1-phenylethanol. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：30 / 33

页数：4

共 36 条

[31] Efficient catalytic conversion of fructose into hydroxymethylfurfural by a novel carbon-based solid acid [J].

Wang, Jianjian ;

Xu, Wenjie ;

Ren, Jiawen ;

Liu, Xiaohui ;

Lu, Guanzhong ;

Wang, Yanqin .

GREEN CHEMISTRY, 2011, 13 (10) :2678-2681

[32] Tuneable porous carbonaceous materials from renewable resources [J].

White, Robin J. ;

Budarin, Vitaly ;

Luque, Rafael ;

Clark, James H. ;

Macquarrie, Duncan J. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (12) :3401-3418

[33] Novel solid acid catalysts: Sulfonic acid group-functionalized mesostructured polymers [J].

Xing, Rong ;

Liu, Na ;

Liu, Yueming ;

Wu, Haihong ;

Jiang, Yongwen ;

Chen, Li ;

He, Mingyuan ;

Wu, Peng .

ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (14) :2455-2461

[34] Development of Biochar-based Catalyst for Transesterification of Canola Oil [J].

Yu, Joyleene T. ;

Dehkhoda, Amir Mehdi ;

Ellis, Naoko .

ENERGY & FUELS, 2011, 25 (01) :337-344

[35] Novel sulfonated carbonaceous materials from p-toluenesulfonic acid/glucose as a high-performance solid-acid catalyst [J].

Zhang, Baohua ;

Ren, Jiawen ;

Liu, Xiaohui ;

Guo, Yun ;

Guo, Yanglong ;

Lu, Guanzhong ;

Wang, Yanqin .

CATALYSIS COMMUNICATIONS, 2010, 11 (07) :629-632

[36]

Zong MH, 2007, GREEN CHEM, V9, P434, DOI 10.1039/b615447f

← 1 2 3 4 →