Liquid-phase dehydration of 1-phenylethanol to styrene over sulfonated D-glucose catalyst

被引：22

作者：

Hasan, Zubair ^{[1
,2
]}

Hwang, Jin-Soo ^{[3
]}

Jhung, Sung Hwa ^{[1
,2
]}

机构：

[1] Kyungpook Natl Univ, Dept Chem, Taegu 702701, South Korea

[2] Kyungpook Natl Univ, Green Nano Mat Res Ctr, Taegu 702701, South Korea

[3] Korea Res Inst Chem Technol, Biorefinerary Res Ctr, Taejon 305600, South Korea

来源：

CATALYSIS COMMUNICATIONS | 2012年 / 26卷

关键词：

Dehydration; Phenylethanol; Styrene; Carbon-based solid acid catalysts; Sulfonation; SOLID-ACID CATALYST; CARBONACEOUS MATERIALS; REACTIVE DISTILLATION; METHANOL CONVERSION; PHENYL-ETHANOL; DEACTIVATION; SAPO-34; ETHER;

D O I：

10.1016/j.catcom.2012.05.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dehydration of 1-phenylethanol to produce styrene has been studied in liquid phase without any solvent with carbon-based solid acid catalysts prepared in one step from renewable resources like D-glucose for the first time. The carbon-based catalyst shows higher styrene selectivity and lower activation energy than other solid acid catalysts that have been used so far, demonstrating that a carbon-based catalyst is very effective in producing styrene from 1-phenylethanol. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：30 / 33

页数：4

共 36 条

[1] Valorisation of corncob residues to functionalised porous carbonaceous materials for the simultaneous esterification/transesterification of waste oils [J].

Arneil Arancon, Rick ;

Barros, Higinio R., Jr. ;

Balu, Alina M. ;

Vargas, Carolina ;

Luque, Rafael .

GREEN CHEMISTRY, 2011, 13 (11) :3162-3167

[2] Liquid-phase dehydration of 1-phenylethanol over mordenite-like zeolites: Influence of Si/Al ratio [J].

Bertero, Nicolas M. ;

Apesteguia, Carlos R. ;

Marchi, Alberto J. .

CATALYSIS COMMUNICATIONS, 2008, 10 (02) :261-265

[3] Liquid-phase dehydration of 1-phenylethanol over HZSM-5: Kinetic modeling [J].

Bertero, Nicolas M. ;

Apesteguia, Carlos R. ;

Marchi, Alberto J. .

CATALYSIS COMMUNICATIONS, 2009, 10 (09) :1339-1344

[4] Versatile mesoporous carbonaceous materials for acid catalysis [J].

Budarin, Vitaly L. ;

Clark, James H. ;

Luque, Rafael ;

Macquarrie, Duncan J. .

CHEMICAL COMMUNICATIONS, 2007, (06) :634-636

[5] Effect of phosphate precursor and organic additives on the structural and catalytic properties of amorphous mesoporous AlPO4 materials [J].

Campelo, JM ;

Jaraba, M ;

Luna, D ;

Luque, R ;

Marinas, JM ;

Romero, AA ;

Navio, JA ;

Macias, M .

CHEMISTRY OF MATERIALS, 2003, 15 (17) :3352-3364

[6] Alternative processes for the production of styrene [J].

Cavani, F ;

Trifiro, F .

APPLIED CATALYSIS A-GENERAL, 1995, 133 (02) :219-239

[7] An overview on the dehydrogenation of alkylbenzenes with carbon dioxide over supported vanadium-antimony oxide catalysts [J].

Chang, Jong-San ;

Hong, Do-Young ;

Vislovskiy, Vladislav P. ;

Park, Sang-Eon .

CATALYSIS SURVEYS FROM ASIA, 2007, 11 (1-2) :59-69

[8] The effect of crystal size of SAPO-34 on the selectivity and deactivation of the MTO reaction [J].

Chen, D ;

Moljord, K ;

Fuglerud, T ;

Holmen, A .

MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 29 (1-2) :191-203

[9] Butan-1-ol and butan-2-ol dehydration on nitrided alurninophosphates: influence of nitridation on reaction pathways (vol 259, pg 269, 2004) [J].

Delsarte, S ;

Grange, P .

APPLIED CATALYSIS A-GENERAL, 2004, 259 (02) :269-279

[10]

Harmer MA, 1998, ADV MATER, V10, P1255, DOI 10.1002/(SICI)1521-4095(199810)10:15<1255::AID-ADMA1255>3.0.CO

← 1 2 3 4 →