(2,9-Dimethyl-1,10-phenanthroline-κ2N,N′)(4-hydroxybenzoato-κ2O,O′)-(nitrato-κO)copper(II)

被引:3
作者
Zhai, Cui-Ping [3 ]
Yan, Feng-Mei [2 ]
Zhao, Pei-Zheng [1 ]
机构
[1] Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
[2] Huanghuai Univ, Dept Chem & Chem Engn, Zhumadian 463000, Peoples R China
[3] Henan Univ, Coll Chem & Chem Engn, Kaifeng 475001, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词
D O I
10.1107/S1600536808034788
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cu(C7H5O3)(NO3)(C14H12N2)], the Cu-II ion is five-coordinated in a slightly distorted square-pyramidal geometry by one O atom of a nitrate anion, two O atoms of a 4-hydroxybenzoate anion, and two N atoms from a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand. In the crystal structure, inversion-related molecules are linked into dimers by O-H center dot center dot center dot O hydrogen bonds. The packing is further stabilized by pi-pi interactions involving the benzene rings of the dmphen and hydroxybenzoate units, with centroid-centroid distances of 3.4930 (14) or 3.5727 (14) angstrom.
引用
收藏
页码:M1479 / U1237
页数:12
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