The electrochemical polymerisation of a [2]rotaxane

被引：11
作者：
Cooke, G
Garety, JF
Mabruk, S
Rabani, G
Rotello, VA
Surpateanu, G
Woisel, P
机构：
[1] Univ Glasgow, WestCHEM, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland
[2] Heriot Watt Univ, Sch Engn & Phys Sci, ScotCHEM, Edinburgh EH14 4AS, Midlothian, Scotland
[3] Univ Massachusetts, Dept Chem, Amherst, MA 01002 USA
[4] Univ Littoral Cote Opale, LabSynth Organ & Environm, F-59140 Dunkerque, France
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 05期
基金：
英国工程与自然科学研究理事会;
关键词：
supramolecular chemistry; rotaxane; electropolymerisation; electrochemistry;
D O I：
10.1016/j.tetlet.2005.11.106
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We report the synthesis of a dithienylpyrrole-stoppered rotaxane and its subsequent electrochemical polymerisation onto a platinum working electrode surface. We have shown that the tetracationic cyclophane moiety of the rotaxane does not impair electropolymerisation of this derivative. Indeed, functionalised films can be conveniently prepared by oxidative polymerisation of the dithienylpyrrole stopper units, to yield a network of rotaxane units interconnected by a conducting polymer backbone. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：783 / 786
页数：4
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