Applications of metal-organic frameworks in adsorption/separation processes via hydrogen bonding interactions

被引：432
作者：
Ahmed, Imteaz
Jhung, Sung Hwa [1 ]
机构：
[1] Kyungpook Natl Univ, Dept Chem, Daegu 41566, South Korea
来源：
CHEMICAL ENGINEERING JOURNAL | 2017年 / 310卷
基金：
新加坡国家研究基金会;
关键词：
Adsorption; Hydrogen bonding; Interaction mechanism; Metal-organic frameworks; NITROGEN-CONTAINING COMPOUNDS; GRAPHITE OXIDE COMPOSITES; DENSITY-FUNCTIONAL THEORY; CENTER-DOT-O; ADSORPTIVE REMOVAL; MODEL FUEL; REACTIVE ADSORPTION; CO2; ADSORPTION; NONCOVALENT INTERACTIONS; REMARKABLE ADSORBENTS;
D O I：
10.1016/j.cej.2016.10.115
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Because of high porosity, diverse functionalities, and easy modification, metal-organic frameworks (MOFs) have important applications in adsorption. Although there are several possible adsorption mechanisms, hydrogen bonding may be one of the significant means among them. Recently, several studies have been carried out which showed successful adsorption over MOFs through hydrogen bonding and therefore its importance should be open to the scientific community for better understanding, new innovations and potential applications etc. Several types of comparatively inert materials, which do not easily interact with other species, can be removed or separated through hydrogen bonding. The present review outlines recent developments in the study of hydrogen bonding interactions between MOF materials and adsorbates. This analysis will motivate the development of methods and techniques to utilize hydrogen bonding in several important adsorption-based applications of MOFs. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：197 / 215
页数：19
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