Recent Advances of Catalytic Asymmetric C-B Bond Forming Reactions

被引:14
|
作者
Huang, Mingyao
Zhu, Shoufei [1 ]
机构
[1] Nankai Univ, Coll Chem, State Key Lab, Tianjin 300071, Peoples R China
来源
基金
中国国家自然科学基金;
关键词
Chiral organoboron; Asymmetric catalysis; C-B bond formation; ALPHA; BETA-UNSATURATED CARBONYL-COMPOUNDS; BORON CONJUGATE ADDITIONS; ENANTIOSELECTIVE SYNTHESIS; ALLYLIC CARBONATES; INSERTION REACTION; EFFICIENT ROUTE; HYDROGEN BONDS; H BONDS; DIBORATION; ALKENES;
D O I
10.7503/cjcu20200090
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Organoboron compounds are of particular importance in the fields of synthesis , pharmaceutical and material sciences. With retention of the absolute configuration, a boryl group can be easily transformed into another functional group , which make chiral organoborons versatile reagents in synthetic chemistry. On the other side , chiral organoborons can serve as drugs or bioactive molecules and applied for the diagnosis and treatment of many diseases. Given these functions , methods for the synthesis of chiral organoboron compounds are intensively investigated in the field of organic synthesis. Herein , we reviewed the recent progresses on the catalytic asymmetric C-B bond forming reactions.
引用
收藏
页码:1426 / 1448
页数:23
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