Membrane properties and anti-bacterial/anti-biofouling activity of polysulfone-graphene oxide composite membranes phase inversed in graphene oxide non-solvent

被引:30
作者
Mokkapati, V. R. S. S. [1 ,2 ]
Koseoglu-Imer, Derya Yuksel [3 ,4 ]
Yilmaz-Deveci, Nurmiray [5 ]
Mijakovic, Ivan [1 ]
Koyuncu, Ismail [3 ,4 ]
机构
[1] Chalmers, Dept Biol & Biol Engn, Kemivagen 10, S-41296 Gothenburg, Sweden
[2] Sabanci Univ, Nanotechnol Res & Applicat Ctr SUNUM, TR-34956 Istanbul, Turkey
[3] Istanbul Tech Univ, Dept Environm Engn, TR-34469 Istanbul, Turkey
[4] Istanbul Tech Univ, Natl Res Ctr Membrane Technol, TR-34469 Istanbul, Turkey
[5] Istanbul Tech Univ, Nanosci & Nanoengn Dept, TR-34469 Istanbul, Turkey
关键词
FORMATION MECHANISM; ULTRAFILTRATION MEMBRANES; SEPARATION PERFORMANCE; COAGULATION BATH; CASTING SOLUTION; WASTE-WATER; MORPHOLOGY; ADDITIVES; HYDROPHILICITY; ANTIBACTERIAL;
D O I
10.1039/c6ra25015g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new and facile method for the fabrication of polysulfone-graphene oxide composite membranes is reported, where after casting, phase inversion is carried out with graphene oxide flakes (GO) in a coagulation bath. The membranes were characterized and the morphology was analysed using scanning electron microscopy. A bacterial inhibition ratio of 74.5% was observed with membranes fabricated from a very low concentration of di-water-GO non-solvent (0.048% of GO). The membranes were successfully tested for permeate flux and fouling resistance using activated sludge filtration from an MBR system. The observed trend shows that GO can operate as a protective barrier for membrane pores against the bacterial community. To our knowledge this is the first time where the immersion precipitation mechanism was carried out in a coagulation bath with GO flakes under continuous stirring. Using this method, a very low concentration of GO is required to fabricate membranes with conventional GO composite membrane properties and better selectivity.
引用
收藏
页码:4378 / 4386
页数:9
相关论文
共 44 条
[1]   Morphology and permeation properties of polysulfone membranes for gas separation: Effects of non-solvent additives and co-solvent [J].
Aroon, M. A. ;
Ismail, A. F. ;
Montazer-Rahmati, M. M. ;
Matsuura, T. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2010, 72 (02) :194-202
[2]   Graphene oxide-embedded thin-film composite reverse osmosis membrane with high flux, anti-biofouling, and chlorine resistance [J].
Chae, Hee-Ro ;
Lee, Jaewoo ;
Lee, Chung-Hak ;
Kim, In-Chul ;
Park, Pyung-Kyu .
JOURNAL OF MEMBRANE SCIENCE, 2015, 483 :128-135
[3]   Enhancing the hydrophilicity and water permeability of polypropylene membranes by nitric acid activation and metal oxide deposition [J].
Chen, He ;
Kong, Liang ;
Wang, Yong .
JOURNAL OF MEMBRANE SCIENCE, 2015, 487 :109-116
[4]  
Craig J.P., 1962, TEXT RES J, V32, P435, DOI DOI 10.1177/004051756203200601
[5]   Effect of additives in the casting solution on the formation of PVDF membranes [J].
Fontananova, E ;
Jansen, JC ;
Cristiano, A ;
Curcio, E ;
Drioli, E .
DESALINATION, 2006, 192 (1-3) :190-197
[6]   Enhanced hydrophilicity and salt rejection study of graphene oxide-polysulfone mixed matrix membrane [J].
Ganesh, B. M. ;
Isloor, Arun M. ;
Ismail, A. F. .
DESALINATION, 2013, 313 :199-207
[7]  
GROBE V, 1959, FASERFORSCH TEXTILTE, V10, P214
[8]   Physical-chemical properties, separation performance, and fouling resistance of mixed-matrix ultrafiltration membranes [J].
Hoek, Eric M. V. ;
Ghosh, Asim K. ;
Huang, Xiaofei ;
Liong, Monty ;
Zink, Jeffrey I. .
DESALINATION, 2011, 283 :89-99
[9]   Tuning Radical Species in Graphene Oxide in Aqueous Solution by Photoirradiation [J].
Hou, Xue-Liang ;
Li, Jing-Liang ;
Drew, Simon C. ;
Tang, Bin ;
Sun, Lu ;
Wang, Xun-Gai .
JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (13) :6788-6793
[10]   Improving the thermal and mechanical properties of polysulfone by incorporation of graphene oxide [J].
Ionita, Mariana ;
Pandele, Andreea Madalina ;
Crica, Livia ;
Pilan, Luisa .
COMPOSITES PART B-ENGINEERING, 2014, 59 :133-139