Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)-H Bonds

被引：242

作者：

Wu, Yinuo ^{[1
,2
]}

Wang, Jun ^{[3
]}

Mao, Fei ^{[2
]}

Kwong, Fuk Yee ^{[1
]}

机构：

[1] Hong Kong Polytech Univ, State Key Lab Chirosci, Dept Appl Biol & Chem Technol, Kowloon, Hong Kong, Peoples R China

[2] Sun Yat Sen Univ, Sch Pharmaceut Sci, Guangzhou 510275, Guangdong, Peoples R China

[3] South Univ Sci & Technol China, Dept Chem, Shenzhen, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2014年 / 9卷 / 01期

关键词：

C-H activation; cross-coupling; dehydrogenation; homogeneous catalysis; palladium; C-H BOND; HYDROGEN SUBSTITUTION-REACTIONS; BETA-KETO-ESTERS; AROMATIC SUBSTITUTION; COUPLING REACTIONS; HECK REACTION; TOLUENE DERIVATIVES; DIRECTING GROUP; ORTHO-ACYLATION; SIMPLE ARENES;

D O I：

10.1002/asia.201300990

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic cross-dehydrogenative coupling (CDC) reaction has received intense attention in recent years. The attractive feature of this coupling process is the formation of a CC bond from two CH moieties under oxidative conditions. In this Focus Review, recent advances in the palladium-catalyzed CDC reactions of C(sp(2))H bond are summarized, with a focus on the period from 2011 to early 2013.

引用

页码：26 / 47

页数：22

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