Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)-H Bonds

被引：242
作者：
Wu, Yinuo [1 ,2 ]
Wang, Jun [3 ]
Mao, Fei [2 ]
Kwong, Fuk Yee [1 ]
机构：
[1] Hong Kong Polytech Univ, State Key Lab Chirosci, Dept Appl Biol & Chem Technol, Kowloon, Hong Kong, Peoples R China
[2] Sun Yat Sen Univ, Sch Pharmaceut Sci, Guangzhou 510275, Guangdong, Peoples R China
[3] South Univ Sci & Technol China, Dept Chem, Shenzhen, Peoples R China
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2014年 / 9卷 / 01期
关键词：
C-H activation; cross-coupling; dehydrogenation; homogeneous catalysis; palladium; C-H BOND; HYDROGEN SUBSTITUTION-REACTIONS; BETA-KETO-ESTERS; AROMATIC SUBSTITUTION; COUPLING REACTIONS; HECK REACTION; TOLUENE DERIVATIVES; DIRECTING GROUP; ORTHO-ACYLATION; SIMPLE ARENES;
D O I：
10.1002/asia.201300990
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The catalytic cross-dehydrogenative coupling (CDC) reaction has received intense attention in recent years. The attractive feature of this coupling process is the formation of a CC bond from two CH moieties under oxidative conditions. In this Focus Review, recent advances in the palladium-catalyzed CDC reactions of C(sp(2))H bond are summarized, with a focus on the period from 2011 to early 2013.
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收藏
页码：26 / 47
页数：22
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