p-tert-Butyltetrathiatetramercaptocalix[4]arene as a sulfur-rich platform for molybdenum, tungsten and nickel

被引：14
作者：
Buccella, Daniela [1 ]
Parkin, Gerard [1 ]
机构：
[1] Columbia Univ, Dept Chem, New York, NY 10027 USA
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 03期
基金：
美国国家科学基金会;
关键词：
C-H BOND; TRANSITION-METAL COMPLEXES; THIOLATE LIGANDS; ELECTRONIC-STRUCTURE; ACTIVATION; CALIXARENE; COORDINATION; MONONUCLEAR; DINUCLEAR; THIACALIXARENE;
D O I：
10.1039/b816066j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
p-tert-Butyltetrathiatetramercaptocalix[4]arene, [S(4)Calix(But)(SH)(4)], reacts with Mo(PMe3)(6), W(PMe3)(4)(eta(2)-CH2PMe2)H and Ni(PMe3)(4) to yield molybdenum, tungsten and nickel compounds in a sulfur-rich coordination environment.
引用
收藏
页码：289 / 291
页数：3
相关论文
共 46 条
[1]  
Agrawal YK, 2004, REV INORG CHEM, V24, P1
[2]   Koilands from thiophiles: mercury(II) clusters from thiacalixarenes [J].
Akdas, H ;
Graf, E ;
Hosseini, MW ;
De Cian, A ;
Bilyk, A ;
Skelton, BW ;
Koutsantonis, GA ;
Murray, I ;
Harrowfield, JM ;
White, AH .
CHEMICAL COMMUNICATIONS, 2002, (10) :1042-1043
[3]  
Akdas H., 2002, J SUPRAMOL CHEM, V2, P21
[4]   Hydroprocessing of heavy petroleum feeds: Tutorial [J].
Ancheyta, J ;
Rana, MS ;
Furimsky, E .
CATALYSIS TODAY, 2005, 109 (1-4) :3-15
[5]   STRUCTURE OF DIAMAGNETIC [W(O-4-ME-C6H4)2CL2(PMEPH2)2] AND COMPARISON WITH RELATED PARAMAGNETIC 2,6-DIPHENYLPHENOXIDO COMPLEXES - A STERIC EFFECT ON PI-BONDING AND ELECTRONIC-STRUCTURE [J].
ATAGI, LM ;
MAYER, JM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (03) :439-441
[6]   CALIXARENES, MACROCYCLES WITH (ALMOST) UNLIMITED POSSIBILITIES [J].
BOHMER, V .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (07) :713-745
[7]   Mononuclear and dinuclear molybdenum and tungsten complexes of p-tert-butyltetrathiacalix[4]arene and p-tert-butyltetrasulfonylcalix[4]arene:: Facile cleavage of the calixarene ligand framework by nickel [J].
Buccella, Daniela ;
Parkin, Gerard .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (27) :8617-+
[8]   Factors influencing coordination versus oxidative addition of C-H bonds to molybdenum and tungsten: Structural and spectroscopic evidence that the calixarene framework promotes C-H bond activation [J].
Buccella, Daniela ;
Tanski, Joseph M. ;
Parkin, Gerard .
ORGANOMETALLICS, 2007, 26 (14) :3275-3278
[9]   p-tert-Butylcalix[4] arene complexes of molybdenum and tungsten:: Reactivity of the calixarene methylene C-H bond and the facile migration of the metal around the phenolic rim of the calixarene [J].
Buccella, Daniela ;
Parkin, Gerard .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (50) :16358-16364
[10]   An investigation into the relative influence of alkoxide and thiolate ligands on the metal-carbon triple bond in X3MCH compounds, where M = Cr, Mo and W and X = OH, SH, OCH3, SCH3, OCF3 and SCF3 from electronic structure calculations [J].
Chisholm, MH ;
Davidson, ER ;
Quinlan, KB .
POLYHEDRON, 2003, 22 (01) :145-152
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