Separation of amino acid enantiomers using supported liquid membrane extraction with chiral phosphates and phosphonates

被引:40
作者
Dzygiel, P
Wieczorek, P
Jonsson, JÅ
Milewska, M
Kafarski, P
机构
[1] Univ Opole, Inst Chem, PL-45052 Opole, Poland
[2] Lund Univ, Dept Analyt Chem, S-22100 Lund, Sweden
[3] Wroclaw Univ Technol, Inst Organ Chem Biochem & Biotechnol, PL-50370 Wroclaw, Poland
关键词
D O I
10.1016/S0040-4020(99)00531-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A series of dialkyl and monoalkyl phosphates, phosphites and phosphinates based on (-)-menthol and (-)-nopol were synthesized and used as carriers for transport of aromatic amino acids through supported liquid membranes. Although all the compounds were found to be effective carriers (with transport rate dependent on their structure) the enantioselectivity of the process obtained was low or moderate. (C) 1999 Elsevier Science Ltd. All rights reserved.
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页码:9923 / 9932
页数:10
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