Gold catalysis in total synthesis

被引:839
作者
Hashmi, A. Stephen K. [1 ]
Rudolph, Matthias [1 ]
机构
[1] Heidelberg Univ, Inst Organ Chem, D-69120 Heidelberg, Germany
关键词
D O I
10.1039/b615629k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this tutorial review directed towards chemists interested in synthesis or catalysis, the application of gold catalysis in total synthesis is summarised and the mode of activation of the substrate by the gold catalyst is discussed.
引用
收藏
页码:1766 / 1775
页数:10
相关论文
共 55 条
[1]   Enantioselective total synthesis of (-)-alpha-kainic acid through free radical cyclization of an alkenyl monothioformimide [J].
Bachi, MD ;
Melman, A .
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (06) :1896-1898
[2]   Aerobic oxidation of glucose II. Catalysis by colloidal gold [J].
Beltrame, P ;
Comotti, M ;
Della Pina, C ;
Rossi, M .
APPLIED CATALYSIS A-GENERAL, 2006, 297 (01) :1-7
[3]   Aerobic oxidation of glucose with gold catalyst: Hydrogen peroxide as intermediate and reagent [J].
Comotti, M ;
Della Pina, C ;
Falletta, E ;
Rossi, M .
ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (03) :313-316
[4]   The catalytic activity of "Naked" gold particles [J].
Comotti, M ;
Della Pina, C ;
Matarrese, R ;
Rossi, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (43) :5812-5815
[5]  
Comotti M., 2004, ANGEW CHEM, V116, P5936
[6]   Generation of aza-ortho-xylylenes via ring opening of 2-(2-acylaminophenyl)aziridines:: Application in the construction of the communesin ring system [J].
Crawley, Seth L. ;
Funk, Raymond L. .
ORGANIC LETTERS, 2006, 8 (18) :3995-3998
[7]   Calculated NMR as a tool for structural elucidation of jungianol and mutisianthol [J].
da Silva, GVJ ;
Neto, AC .
TETRAHEDRON, 2005, 61 (32) :7763-7767
[8]   Total synthesis of heliophenanthrone [J].
Dyker, G ;
Hildebrandt, D .
JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (15) :6093-6096
[9]  
Fehr, 2006, ANGEW CHEM, V118, P2967
[10]   Synthesis of (-)-cubebol by face-selective platinum-, gold-, or copper-catalyzed cycloisomerization: Evidence for chirality transfer [J].
Fehr, Charles ;
Galindo, Jose .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (18) :2901-2904