Volumetric Properties of the Ternary System Dimethyl Carbonate plus Butyl Methacrylate plus Allyl Methacrylate and Its Binary Butyl Methacrylate plus Allyl Methacrylate at 293.15 K and p=101.325 kPa

被引：1

作者：

Wisniak, Jaime ^{[1
]}

Cortez, Gladis ^{[2
]}

Peralta, Rene D. ^{[2
]}

Infante, Ramiro ^{[2
]}

Elizalde, Luis E. ^{[2
]}

Amaro, Tlaloc A. ^{[3
]}

Garcia, Omar ^{[3
]}

Soto, Homero ^{[3
]}

机构：

[1] Ben Gurion Univ Negev, Dept Chem Engn, IL-84105 Beer Sheva, Israel

[2] Ctr Invest Quim Aplicada, Saltillo 25253, Coahuila, Mexico

[3] Univ Autonoma Coahuila, Fac Ciencias Quim, Saltillo 25280, Coahuila, Mexico

来源：

JOURNAL OF SOLUTION CHEMISTRY | 2012年 / 41卷 / 09期

关键词：

Densities; Excess molar volumes; Dimethyl carbonate; Methacrylates; Ternary systems; METHYL-METHACRYLATE; ETHYL ACRYLATE; EXCESS VOLUMES; STYRENE; MIXTURES; DENSITY;

D O I：

10.1007/s10953-012-9892-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Densities of the ternary system dimethyl carbonate + butyl methacrylate + allyl methacrylate and its binary subsystem butyl methacrylate + allyl methacrylate have been measured in the whole composition range, at 293.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess molar volumes of the binary system are positive and were correlated with the Redlich-Kister equation and with a series of Legendre polynomials. Several models were used to correlate ternary behavior from the excess molar volume data of their constituent binaries and found to fit the data equally well. The best fit was based on a direct approach, without information on the component binary systems.

引用

页码：1631 / 1648

页数：18

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