Hydrothermal synthesis and crystal structure of a novel rare-earth tungsten phosphate supramolecular compound

被引：0

作者：

Shu, Qi-Xia ^{[1
]}

Sun, Guo-Yuan ^{[2
]}

Wang, Xiao-Bo ^{[1
]}

Hu, Xue-Lei ^{[1
]}

机构：

[1] Wuhan Inst Technol, Key Lab Green Chem Proc, Minist Educ, Hubei Key Lab Novel Chem Reactor & Green Chem Tec, Wuhan 430073, Peoples R China

[2] N China Univ Water Conservancy & Elect Power, Sch Mech Engn, Zhengzhou 450011, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 21卷

关键词：

Hydrothermal synthesis; Polyoxometalates; Crystal structure; COMPLEXES; DAWSON;

D O I：

10.1016/j.inoche.2012.04.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new polyoxometalate (H(2)bpy)(2){Eu(H2O)(3)(PW11O39)}center dot 6H(2)O 1 constructed from lacunary Keggin frameworks, has been hydrothermally synthesized and characterized by IR and X-ray single crystal diffraction. It is interesting to find that the heteropolyanions are linked to chains, and the chains are further connected into an extensive two dimension (2D) layer structure depending on hydrogen bond. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：47 / 49

页数：3

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