Densification Kinetics of Nanocrystalline Zirconia Powder Using Microwave and Spark Plasma Sintering-A Comparative Study

被引:13
作者
Vasylkiv, Oleg [1 ,2 ]
Demirskyi, Dmytro [3 ]
Sakka, Yoshio [1 ]
Ragulya, Andrey [3 ]
Borodianska, Hanna [1 ,2 ,3 ]
机构
[1] Natl Inst Mat Sci, Tsukuba, Ibaraki 3050047, Japan
[2] Nanyang Technol Univ, Singapore 639798, Singapore
[3] Inst Problems Mat Sci NASU, UA-03680 Kiev, Ukraine
关键词
Microwave Processing; SPS; Sintering; Zirconia; Ceramics; NECK GROWTH-KINETICS; DC ELECTRIC-FIELD; CUBIC ZIRCONIA; INITIAL-STAGE; GRAIN-GROWTH; TEMPERATURE; NANOMATERIALS; NANOPOWDERS; CERAMICS; ALUMINA;
D O I
10.1166/jnn.2012.6177
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two-stage densification process of nanosized 3 mol% yttria-stabilized zirconia (3Y-SZ) polycrystalline compacts during consolidation via microwave and spark-plasma sintering have been observed. The values of activation energies obtained for microwave and spark-plasma sintering 260-275 kJ.mol(-1) are quite similar to that of conventional sintering of zirconia, suggesting that densification during initial stage is controlled by the grain-boundary diffusion mechanism. The sintering behavior during microwave sintering was significantly affected by preliminary pressing conditions, as the surface diffusion mechanism (230 kJ.mol(-1)) is active in case of cold-isostatic pressing procedure was applied.
引用
收藏
页码:4577 / 4582
页数:6
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