Facile synthesis of sesame-husk-like porous SnO2 nanocylinders as anodes for high-performance lithium-ion batteries

被引:2
作者
Dai, Peng [1 ]
Hu, Haibo [1 ]
Jiang, Tongtong [1 ]
Yu, Xinxin [1 ]
Bai, Zhiman [1 ]
Wu, Mingzai [1 ]
机构
[1] Anhui Univ, Sch Phys & Mat Sci, Hefei 230601, Anhui, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
calcination; lithium compounds; electrochemical electrodes; nanoporous materials; secondary cells; current density; tin compounds; porous nanostructures; lithium-ion batteries; refluxed technique; sesame-husk-like porous nanocylinder anode material synthesis; cyclability; electrochemical performance; SnO2; HOLLOW MICROSPHERES; NANOSHEETS;
D O I
10.1049/mnl.2018.5419
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Sesame-husk-like porous SnO2 nanocylinders were synthesised by a refluxed technique followed calcination in air. Served as anode materials for lithium-ion batteries, porous SnO2 nanocylinders showed a higher initial discharge capacity of 2411.3 mAh/g at 100 mA/g compared with non-porous SnO2 nanocylinders (2043.6 mAh/g). Moreover, porous SnO2 nanocylinders demonstrated better cyclability and rate capability in comparison with non-porous SnO2 nanocylinders. For porous SnO2 nanocylinders, a higher discharge capacity of 414.5 mAh/g after 50 cycles at a current density of 100 mA/g can be successfully delivered, and a higher reversible capacity of 248.3 mAh/g at 1000 mA/g current density after 100 cycles could be retained. The improved electrochemical performance is mainly ascribed to the unique porous nanostructures.
引用
收藏
页码:178 / 181
页数:4
相关论文
共 19 条
  • [1] Porous Electrode Materials for Lithium-Ion Batteries - How to Prepare Them and What Makes Them Special
    Anh Vu
    Qian, Yuqiang
    Stein, Andreas
    [J]. ADVANCED ENERGY MATERIALS, 2012, 2 (09) : 1056 - 1085
  • [2] Photoelectron Spectroscopic Evidence for Overlapping Redox Reactions for SnO2 Electrodes in Lithium-Ion Batteries
    Bohme, Solveig
    Philippe, Bertrand
    Edstrom, Kristina
    Nyholm, Leif
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121 (09) : 4924 - 4936
  • [3] Ordered mesoporous materials for lithium-ion batteries
    Eftekhari, Ali
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2017, 243 : 355 - 369
  • [4] Preparation of PPy-Coated MnO2 Hybrid Micromaterials and Their Improved Cyclic Performance as Anode for Lithium-Ion Batteries
    Feng, Lili
    Zhang, Yinyin
    Wang, Rui
    Zhang, Yanli
    Bai, Wei
    Ji, Siping
    Xuan, Zhewen
    Yang, Jianhua
    Zheng, Ziguang
    Guan, Hongjin
    [J]. NANOSCALE RESEARCH LETTERS, 2017, 12
  • [5] Preparation of octahedral CuO micro/nanocrystals and electrochemical performance as anode for lithium-ion battery
    Feng, Lili
    Xuan, Zhewen
    Bai, Yang
    Zhao, Hongbo
    Li, Li
    Chen, Yashun
    Yang, Xianqin
    Su, Changwei
    Guo, Junming
    Chen, Xiaokai
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 600 : 162 - 167
  • [6] Unveiling origin of additional capacity of SnO2 anode in lithium-ion batteries by realistic ex situ TEM analysis
    Lee, Seung-Yong
    Park, Kyu-Young
    Kim, Won-Sik
    Yoon, Sangmoon
    Hong, Seong-Hyeon
    Kang, Kisuk
    Kim, Miyoung
    [J]. NANO ENERGY, 2016, 19 : 234 - 245
  • [7] Porous SnO2 hollow microspheres as anodes for high-performance lithium ion battery
    Li, Haojie
    Su, Qingmei
    Kang, Jinwei
    Huang, Min
    Feng, Miao
    Feng, Huagui
    Huang, Ping
    Du, Gaohui
    [J]. MATERIALS LETTERS, 2018, 217 : 276 - 280
  • [8] Electrospun porous SnO2 nanotubes as high capacity anode materials for lithium ion batteries
    Li, Limiao
    Yin, Xiaoming
    Liu, Shuang
    Wang, Yanguo
    Chen, Libao
    Wang, Taihong
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (10) : 1383 - 1386
  • [9] Hydrothermal synthesis of hollow SnO2 spheres with excellent electrochemical performance for anodes in lithium ion batteries
    Liu, Ruiping
    Su, Weiming
    Shen, Chao
    Iocozzia, James
    Zhao, Shiqiang
    Yuan, Kunjie
    Zhang, Ning
    Wang, Chang-an
    Lin, Zhiqun
    [J]. MATERIALS RESEARCH BULLETIN, 2017, 96 : 443 - 448
  • [10] Surfactant-free microwave hydrothermal synthesis of SnO2 nanosheets as an anode material for lithium battery applications
    Narsimulu, D.
    Vinoth, S.
    Srinadhu, E. S.
    Satyanarayana, N.
    [J]. CERAMICS INTERNATIONAL, 2018, 44 (01) : 201 - 207