Synthesis of poly(lactic acid-b-p-dioxanone) block copolymers from ring opening polymerization of p-dioxanone by poly(L-lactic acid) macroinitiators

被引：22

作者：

Li, Bin ^{[1
]}

Chen, Si-Chong ^{[1
]}

Qiu, Zhi-Cheng ^{[1
]}

Yang, Qiu Ke-Ke ^{[1
]}

Tang, Song-Ping ^{[1
]}

Yu, Wen-Jing ^{[1
]}

Wang, Yu-Zhong ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Ctr Degradable & Flame Retardant Polymer Mat, Chengdu 610064, Peoples R China

来源：

POLYMER BULLETIN | 2008年 / 61卷 / 02期

关键词：

poly(lactic acid); poly(p-dioxanone); block copolymer; biodegradable;

D O I：

10.1007/s00289-008-0939-1

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(lactic acid-b-p-dioxanone) block copolymers (P(LA-b-PDO)) were synthesized by ring-opening polymerization of p-dioxanone using poly(lactic acid) (PLA) with different molecular weights as macroinitiators in N(2) atmosphere. The copolymers were characterized by (1)H-NMR spectra. The thermal and crystalline behaviors and thermal stability of these copolymers were investigated by DSC, TGA and WAXD. The results indicated that the contents of each segment and the intrinsic viscosities affected the properties of copolymers obviously.

引用

页码：139 / 146

页数：8

共 22 条

[1] Nucleation and crystallization in double crystalline poly(p-dioxanone)-b-poly(ε-caprolactone) diblock copolymers [J].

Albuerne, J ;

Márquez, L ;

Müller, AJ ;

Raquez, JM ;

Degée, P ;

Dubois, P ;

Castelletto, V ;

Hamley, IW .

MACROMOLECULES, 2003, 36 (05) :1633-1644

[2] A novel biodegradable poly(p-dioxanone)-grafted poly(vinyl alcohol) copolymer with a controllable in vitro degradation [J].

Chen, SC ;

Zhou, ZX ;

Wang, YZ ;

Wang, XL ;

Yang, KK .

POLYMER, 2006, 47 (01) :32-36

[3]

Doddi N, 1977, United States patent, Patent No. [US 4032 988(A1), 4032988, 4, 032, 988]

[4]

FORSCHNER TC, 1997, Patent No. 9721753

[5]

Kim KW, 2002, MACROMOL CHEM PHYS, V203, P2245, DOI 10.1002/1521-3935(200211)203:15<2245::AID-MACP2245>3.0.CO

[6]

2-3

[7]

LIPINSKY ES, 1993, Patent No. 5767222

[8]

Narayan B, 2003, POLYM INT, V52, P6

[9]

NARAYAN B, 2002, POLYM DEGRAD STABIL, V78, P423

[10]

NARAYAN B, 2003, J POLYM SCI POL LETT, V41, P1955

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