Liquid-liquid equilibria containing fluorous solvents as environmentally benign solvent

被引：5
|
作者：
Matsuda, Hiroyuki [1 ]
Hirota, Yuki [1 ]
Kurihara, Kiyofumi [1 ]
Tochigi, Katsumi [1 ]
Ochi, Kenji [1 ]
机构：
[1] Nihon Univ, Dept Mat & Appl Chem, Chiyoda Ku, Tokyo 1018308, Japan
来源：
FLUID PHASE EQUILIBRIA | 2013年 / 357卷
关键词：
Liquid-liquid equilibria; Fluorous solvent; Activity coefficient model;
D O I：
10.1016/j.fluid.2012.12.037
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The object of this study is to measure the liquid-liquid equilibrium (LLE) data in fluorous solvent (perfluorohexane and Galden (R) HT-135) mixtures, which are used as environmentally benign reaction solvents. The LLE data of perfluorohexane + n-alkane (C-7, C-9, and C-10) mixtures were measured to determine the phase behavior of perfluorohexane+ n-alkane (C-6-C-10) mixtures. The LLE for Galden HT-135 (R) + dibutyl ether/butyl acetate mixtures were measured up to the upper critical solution temperature (UCST). The experimental results for the LLE were represented using the NRTL activity coefficient model. (C) 2013 Elsevier B.V. All rights reserved,
引用
收藏
页码：71 / 75
页数：5
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